Strategy Combining Free Volume Theory and Fragment Contribution Corresponding State Method for Predicting Viscosities of Ionic Liquids
文献类型：期刊论文
| 作者 | Tu, Wenhui1,2; Zeng, Shaojuan1; Zhang, Xiaochun1; He, Xuezhong3; Liu, Lei1; Zhang, Suojiang1,2; Zhang, Xiangping1,2,4 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2019-04-10 |
| 卷号 | 58期号:14页码:5640-5649 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.8b06255 |
| 英文摘要 | In this study, we proposed a strategy that combines the fragment contribution corresponding states (FCCS) and free volume theory (FVT) method, namely FCCS-FVT, to calculate the viscosities of ionic liquids (ILs) covering a wide range of temperatures and pressures. In the method, the FCCS model was used to calculate the critical properties and densities of ILs, and then based on those values, the FVT model was applied to calculate the viscosities of ILs. The results indicated that the FCCS-FVT method shows high accuracy with 6.6% in average absolute relative deviation of total 2138 data points (25 ILs), which covers a wide range of temperatures (258.15-573 K) and pressures (0.06-300 MPa). Moreover, it is more convenient for the FCCS-FVT method to be applied for quick and accurate calculation of viscosities of ILs because it needs only three adjustable parameters. |
| WOS关键词 | GROUP-CONTRIBUTION MODEL ; THERMOPHYSICAL PROPERTIES ; PRESSURE-DEPENDENCE ; PHYSICAL-PROPERTIES ; BINARY-MIXTURES ; 1-HEXYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE ; 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE ; PHYSICOCHEMICAL PROPERTIES ; TEMPERATURE-DEPENDENCE ; REFRACTIVE-INDEXES |
| 资助项目 | National Key R&D Program of China[2017YFB0603301] ; Key Program of National Natural Science Foundation of China[21838010] ; National Natural Scientific Foundation of China[U1704251] ; National Natural Scientific Foundation of China[21676271] ; National Natural Scientific Foundation of China[21890764] ; DNL Cooperation Fund, CAS[DNL 180406] ; Research Council of Norway (CO2Hing)[267615] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000464769200030 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; Key Program of National Natural Science Foundation of China ; National Natural Scientific Foundation of China ; DNL Cooperation Fund, CAS ; Research Council of Norway (CO2Hing) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28243]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zeng, Shaojuan; Zhang, Xiangping |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn,State Key Lab Multiphas, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China 3.Norwegian Univ Sci & Technol, Dept Chem Engn, NO-7491 Trondheim, Norway 4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tu, Wenhui,Zeng, Shaojuan,Zhang, Xiaochun,et al. Strategy Combining Free Volume Theory and Fragment Contribution Corresponding State Method for Predicting Viscosities of Ionic Liquids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(14):5640-5649. |
| APA | Tu, Wenhui.,Zeng, Shaojuan.,Zhang, Xiaochun.,He, Xuezhong.,Liu, Lei.,...&Zhang, Xiangping.(2019).Strategy Combining Free Volume Theory and Fragment Contribution Corresponding State Method for Predicting Viscosities of Ionic Liquids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(14),5640-5649. |
| MLA | Tu, Wenhui,et al."Strategy Combining Free Volume Theory and Fragment Contribution Corresponding State Method for Predicting Viscosities of Ionic Liquids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.14(2019):5640-5649. |
入库方式： OAI收割
来源：过程工程研究所
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