Solubility Determination and Thermodynamic Modeling for the System NaCl-NH4Cl-Diethanolamine-H2O
文献类型：期刊论文
| 作者 | Wang, Qiaoxin1,2; Li, Zhibao1 |
| 刊名 | JOURNAL OF CHEMICAL AND ENGINEERING DATA
 |
| 出版日期 | 2019-03-01 |
| 卷号 | 64期号:3页码:895-904 |
| ISSN号 | 0021-9568 |
| DOI | 10.1021/acs.jced.8b00515 |
| 英文摘要 | In this work, the solubility behavior of salts NaCl and NH4Cl was investigated in aqueous diethanolamine (DEA) solution by varying both temperature and the solvent composition. DEA has been prevalently used in the postcombustion process to capture CO2, but a limited amount of references can be found pertaining to any solid liquid system containing DEA. It was experimentally determined that the solubility of NaCl decreases, whereas the solubility of NH4Cl increases with the addition of DEA (x'(DEA) = 0-0.2). The solubility of both salts increases if temperature is raised from 283 to 353 K. The common-ion effect was examined for the quaternary system when both salts are present in the solution. By the regression of solubility data with the Mixed Solvent Electrolyte model, we proved that readjusting the middle-range interaction parameters between Cl--DEA and DEAH(+)-Cl- would lower the relative deviation (within 5%) for each proposed ternary system. A comprehensive chemical model was further constructed based on the newly adjusted interaction parameters, provided to further analyze system equilibria, as well as the activity coefficients for aqueous electrolytes. |
| WOS关键词 | PARTIAL MOLAL PROPERTIES ; HIGH-PRESSURES ; EQUILIBRIUM-CONSTANT ; TRANSPORT-PROPERTIES ; AQUEOUS-SOLUTIONS ; CARBON-DIOXIDE ; CO2 ; ELECTROLYTES ; TEMPERATURES ; MONOETHANOLAMINE |
| 资助项目 | National Science Foundation of China[21506218] ; National Science Foundation of China[21476235] ; National Science Foundation of China[U1407112] |
| WOS研究方向 | Thermodynamics ; Chemistry ; Engineering |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000461537300005 |
| 资助机构 | National Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28316]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Li, Zhibao |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Dept Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qiaoxin,Li, Zhibao. Solubility Determination and Thermodynamic Modeling for the System NaCl-NH4Cl-Diethanolamine-H2O[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2019,64(3):895-904. |
| APA | Wang, Qiaoxin,&Li, Zhibao.(2019).Solubility Determination and Thermodynamic Modeling for the System NaCl-NH4Cl-Diethanolamine-H2O.JOURNAL OF CHEMICAL AND ENGINEERING DATA,64(3),895-904. |
| MLA | Wang, Qiaoxin,et al."Solubility Determination and Thermodynamic Modeling for the System NaCl-NH4Cl-Diethanolamine-H2O".JOURNAL OF CHEMICAL AND ENGINEERING DATA 64.3(2019):895-904. |
入库方式： OAI收割
来源：过程工程研究所
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