Preparation process of magnesium alloys by complex salt dehydration-electrochemical codeposition
文献类型：期刊论文
| 作者 | Zhang, Zhimin; Lu, Xuchen |
| 刊名 | MATERIALS AND MANUFACTURING PROCESSES
 |
| 出版日期 | 2019 |
| 卷号 | 34期号:6页码:591-597 |
| 关键词 | magnesium alloys dehydration hydrolysis electrochemical |
| ISSN号 | 1042-6914 |
| DOI | 10.1080/10426914.2019.1566616 |
| 英文摘要 | High-purity anhydrous MgCl2-containing molten salt was directly synthesized from MgCl(2)6H(2)O via complex salts dehydration and protection. After that, Mg-Al and Mg-Zn alloys were prepared by electrochemical codeposition. The hydrolysis processes of magnesium chloride hexahydrate in various chloride mixtures were studied. Then, the preparation process was studied and the dehydration mechanism was put forward. NH(4)ClMgCl(2)nH(2)O formed under 300 degrees C inhibits the formation of hydrolysate during the dehydration process. KMgCl3 and K3NaMgCl6 formed above 400 degrees C can further protect the unstable anhydrous MgCl2. Therefore, high-purity anhydrous MgCl2-containing molten salt with w(MgO)/w(MgCl2) being 0.016wt.% was obtained. The current efficiency was above 81% and 97%, respectively, when preparing Mg-Al alloys and Mg-Zn alloys, and the alloying elements were distributed homogeneously in the alloy matrix. |
| WOS关键词 | CHLORIDE ; MG ; LI |
| 资助项目 | National Natural Science Foundation of China[51501178] ; State Key Laboratory of Multiphase Complex Systems[MPCS-2017-D-09] ; State Key Laboratory of Multiphase Complex Systems[MPCS-2017-A-05] |
| WOS研究方向 | Engineering ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000461529400001 |
| 出版者 | TAYLOR & FRANCIS INC |
| 资助机构 | National Natural Science Foundation of China ; State Key Laboratory of Multiphase Complex Systems |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28361]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Lu, Xuchen |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zhimin,Lu, Xuchen. Preparation process of magnesium alloys by complex salt dehydration-electrochemical codeposition[J]. MATERIALS AND MANUFACTURING PROCESSES,2019,34(6):591-597. |
| APA | Zhang, Zhimin,&Lu, Xuchen.(2019).Preparation process of magnesium alloys by complex salt dehydration-electrochemical codeposition.MATERIALS AND MANUFACTURING PROCESSES,34(6),591-597. |
| MLA | Zhang, Zhimin,et al."Preparation process of magnesium alloys by complex salt dehydration-electrochemical codeposition".MATERIALS AND MANUFACTURING PROCESSES 34.6(2019):591-597. |
入库方式： OAI收割
来源：过程工程研究所
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