Catalytic oxidation of ethyl acetate over Ru-Cu bimetallic catalysts: Further insights into reaction mechanism via in situ FTIR and DFT studies
文献类型：期刊论文
| 作者 | Liu, Xiaolong1; Han, Qingzhen1; Shi, Wenbo1; Zhang, Cheng1; Li, Erwei1; Zhu, Tingyu1,2 |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2019 |
| 卷号 | 369页码:482-492 |
| 关键词 | Oxygenated volatile organic compounds Ethyl acetate Catalytic oxidation Ruthenium Bimetallic catalysts |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2018.11.025 |
| 英文摘要 | In this work, ruthenium-based bimetallic catalysts of 1Ru-5 M/TiO2 (M = Co, Ce, Fe, Mn, Cu, Ni) were prepared and evaluated in ethyl acetate oxidation. It was found that 1Ru-5Cu/TiO2 gave the highest catalytic activity. The influence of CuO content and the preparation method on the catalytic activity was also studied. 1Ru-5Cu/TiO2 showed great catalytic stability in the on-stream reaction test. The influence of H2O on the catalytic activity is presented. The bimetallic catalyst 1Ru-5Cu/TiO2 showed better catalytic performance than the monometallic catalysts 1Ru/TiO2 and 5Cu/TiO2. XRD, TEM, HAADF-STEM, H-2-TPR, and XPS characterizations were conducted, and the synergistic effect between Ru and Cu was well presented. In situ FTIR studies were also conducted, and the reaction intermediates were revealed on the catalyst surface. The theoretical calculations suggested that ethyl acetate is more easily adsorbed on the CuO surface, while it reacts more easily on the RuO2 surface. Accordingly, a reaction mechanism for the catalytic oxidation of ethyl acetate over a Ru-Cu bimetallic catalyst is proposed. (C) 2018 Elsevier Inc. All rights reserved. |
| WOS关键词 | VOLATILE ORGANIC-COMPOUNDS ; HIGH-PERFORMANCE ; CARBON-MONOXIDE ; BINARY OXIDES ; COMBUSTION ; BENZENE ; ETHANOL ; COPPER ; CERIA ; CO |
| 资助项目 | Natural Science Foundation of China[21607154] ; Natural Science Foundation of China[11504374] ; National Key Research and Development Program of China[2017YFC0210304] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000460711700049 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Natural Science Foundation of China ; National Key Research and Development Program of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28363]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Xiaolong; Zhu, Tingyu |
| 作者单位 | 1.Chinese Acad Sci, Beijing Engn Res Ctr Proc Pollut Control, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Ctr Excellence Reg Atmospher Environm, Inst Urban Environm, Xiamen 361021, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiaolong,Han, Qingzhen,Shi, Wenbo,et al. Catalytic oxidation of ethyl acetate over Ru-Cu bimetallic catalysts: Further insights into reaction mechanism via in situ FTIR and DFT studies[J]. JOURNAL OF CATALYSIS,2019,369:482-492. |
| APA | Liu, Xiaolong,Han, Qingzhen,Shi, Wenbo,Zhang, Cheng,Li, Erwei,&Zhu, Tingyu.(2019).Catalytic oxidation of ethyl acetate over Ru-Cu bimetallic catalysts: Further insights into reaction mechanism via in situ FTIR and DFT studies.JOURNAL OF CATALYSIS,369,482-492. |
| MLA | Liu, Xiaolong,et al."Catalytic oxidation of ethyl acetate over Ru-Cu bimetallic catalysts: Further insights into reaction mechanism via in situ FTIR and DFT studies".JOURNAL OF CATALYSIS 369(2019):482-492. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。