Synergistic effect for promoted benzene oxidation over monolithic CoMnAlO catalysts derived from in situ supported LDH film
文献类型：会议论文
| 作者 | Li, Shuangde1; Mo, Shengpeng1,2; Wang, Dongdong1,2; Wu, Xiaofeng1; Chen, Yunfa1,3
|
| 出版日期 | 2019-07-15 |
| 会议日期 | DEC 05-06, 2017 |
| 会议地点 | Tsukuba, JAPAN |
| 关键词 | Monolithic film LDH Catalytic oxidation Reaction rate Synergistic effect |
| 卷号 | 332 |
| DOI | 10.1016/j.cattod.2018.08.014 |
| 页码 | 132-138 |
| 英文摘要 | Monolithic catalysts with high catalytic activity bring about increasing interest in practical environmental purification field for volatile organic compounds (VOCs) degradation with low pressure drops. Monolithic CoMnAlO catalysts with varied Co/Mn molar ratio derived from in situ supported layered double hydroxides (LDH) film are prepared through ammonia hydrothermal growing on Al substrate following calcinations. The textural properties for CoMnAlO catalysts with low temperature reducibility, surface element species are controlled by tuning the initial Co/Mn molar ratio verified through H-2-TPR and XPS spectra. CoMn2AlO film sample shows best activity with the temperature for 90% benzene decomposition (T-90) around 238 degrees C with space velocity 300,000 ml g(cat)(-1) h(-1). The reaction rate of CoMn2AlO film is about 1.32 mmol g(cat)(-1) h(-1) at 260 degrees C with T-99, which is nearly two times to that of Co3AlO film catalyst with 0.73 mmol g(cat)(-1) h(-1), because of the higher Mn4+/Mn3+ and Co3+/Co2+ atomic ratios and reducibility inducing by the synergistic effect of Co and Mn. The value is five times higher than CoMn2AlO powder catalyst with 0.26 mmol g(cat)(-1) h(-1), which is due to the great exposure active sites. |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Open Research Fund of State Key Laboratory of Multi-phase Complex Systems |
| 会议录 | CATALYSIS TODAY
 |
| 会议录出版者 | ELSEVIER SCIENCE BV |
| 语种 | 英语 |
| 资助项目 | National Key R&D Program of China[2017YFC0211503] ; National Natural Science Foundation of China[21401200] ; National Natural Science Foundation of China[51672273] ; Open Research Fund of State Key Laboratory of Multi-phase Complex Systems[MPCS-2017-D-06] |
| ISSN号 | 0920-5861 |
| WOS研究方向 | Chemistry ; Engineering |
| WOS记录号 | WOS:000468158600020 |
| WOS关键词 | VOLATILE ORGANIC-COMPOUNDS ; LAYERED DOUBLE HYDROXIDES ; MN ; CO ; OXIDES ; VOCS ; PERFORMANCE ; SUBSTITUTION ; TEMPERATURE ; COMBUSTION |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/28943]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Chen, Yunfa |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Urban Atmospher Environm, Xiamen 361021, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Shuangde,Mo, Shengpeng,Wang, Dongdong,et al. Synergistic effect for promoted benzene oxidation over monolithic CoMnAlO catalysts derived from in situ supported LDH film[C]. 见:. Tsukuba, JAPAN. DEC 05-06, 2017. |
入库方式： OAI收割
来源：过程工程研究所
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