Terminal group engineering for small-molecule donors boosts the performance of nonfullerene organic solar cells
文献类型：期刊论文
| 作者 | Duan, Tainan1 ; Tang, Hua1,2; Liang, Ru-Ze2; Lv, Jie1; Kan, Zhipeng1,2; Singh, Ranbir3; Kumar, Manish4; Xiao, Zeyun1; Lu, Shirong1; Laquai, Frederic2
|
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2019-02-14 |
| 卷号 | 7期号:6页码:2541-2546 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta11420j |
| 通讯作者 | Liang, Ru-Ze(ruze.liang@kaust.edu.sa) ; Kan, Zhipeng(kanzhipeng@cigit.ac.cn) ; Lu, Shirong(lushirong@cigit.ac.cn) |
| 英文摘要 | Nonfullerene acceptors propelled organic solar cell power conversion efficiencies (PCE) to above 15%. However, most of the reported nonfullerene systems with a PCE >10% are composed of polymer donors and small-molecule acceptors, while only a few small molecule (SM) donors have been reported. Herein, two new smallmolecule donors namely BDT-RO and BDT-RN with esterified rhodanine (ER) as the terminal group are reported. The widely used fused-ring acceptor IDIC is chosen to fabricate all-small-molecule solar cells with the new donors. A high PCE of over 9.0% is achieved with BDT-RO, while its isomer BDT-RN shows a PCE close to 8.4%. Comparison with the common small molecule donor DR3TBDTT using the same conditions yielded lower performance (7.6% with IDIC), indicating an 18% enhancement in PCE could be achieved through end group engineering. The efficiency differences are attributed to the different morphology and phase separation resulting from the crystallinity and aggregation ability of the donors. The results demonstrate that ER is a promising building block when designing SM donors for all-small-molecule systems. |
| 资助项目 | National Natural Science Foundation of China[61805245] ; National Natural Science Foundation of China[21702202] ; CAS Pioneer Hundred Talents Program[Y82A060Q10] ; Recruitment Program of Global Experts[R52A199Z10] ; Youth Innovation Fund[Y82Z330Q10] ; Natural Science Foundation of Chongqing[cstc2015jcyjB0628] ; Natural Science Foundation of Chongqing[cstc2017rgznzdyfX0030] ; King Abdullah University of Science and Technology (KAUST) |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000457893400011 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.138/handle/2HOD01W0/7379]  |
| 专题 | 有机半导体材料研究中心 |
| 通讯作者 | Liang, Ru-Ze; Kan, Zhipeng; Lu, Shirong |
| 作者单位 | 1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 2.KAUST, KAUST Solar Ctr KSC, Phys Sci & Engn Div, Thuwal 239556900, Saudi Arabia 3.Dongguk Univ, Dept Energy & Mat Engn, Seoul, South Korea 4.Pohang Univ Sci & Technol, Pohang Accelerator Lab, Pohang 790784, South Korea |
| 推荐引用方式 GB/T 7714 | Duan, Tainan,Tang, Hua,Liang, Ru-Ze,et al. Terminal group engineering for small-molecule donors boosts the performance of nonfullerene organic solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2019,7(6):2541-2546. |
| APA | Duan, Tainan.,Tang, Hua.,Liang, Ru-Ze.,Lv, Jie.,Kan, Zhipeng.,...&Laquai, Frederic.(2019).Terminal group engineering for small-molecule donors boosts the performance of nonfullerene organic solar cells.JOURNAL OF MATERIALS CHEMISTRY A,7(6),2541-2546. |
| MLA | Duan, Tainan,et al."Terminal group engineering for small-molecule donors boosts the performance of nonfullerene organic solar cells".JOURNAL OF MATERIALS CHEMISTRY A 7.6(2019):2541-2546. |
入库方式： OAI收割
来源：重庆绿色智能技术研究院
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。