Organic Base-Catalyzed C-S Bond Construction from CO2: A New Route for the Synthesis of Benzothiazolones
文献类型：期刊论文
| 作者 | Gao, Xiang1; Deng, Yuehua1; Lu, Changyu1; Zhang, Lei1; Wang, Xintao1; Yu, Bo2 |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2018-07-01 |
| 卷号 | 8期号:7 |
| ISSN号 | 2073-4344 |
| 关键词 | Organic Bases C-s Bonds Carbon Dioxide Benzothiazolones |
| DOI | 10.3390/catal8070271 |
| 英文摘要 | The synthesis of organosulfur compounds via the construction of C-S bonds using CO2 as a C1 resource is very interesting. Herein, a novel method of synthesizing benzothiazolones via the cyclocarbonylation of 2-aminothiophenols with CO2 was developed. A series of organic bases was investigated for the catalysis of cyclocarbonylation, and 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) displayed the best catalytic activity. Then, various reaction parameters such as CO2 pressure, temperature, amount of catalyst, and reaction time for the catalytic performance were studied. Finally, a series of benzothiazolones was synthesized under the optimal reaction conditions, and a possible catalytic mechanism was also proposed. |
| 语种 | 英语 |
| 出版者 | MDPI |
| WOS记录号 | WOS:000440016400018 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41923]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yu, Bo |
| 作者单位 | 1.Xian Univ Sci & Technol, Coll Geol & Environm, Xian 710054, Shaanxi, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Colloid Interface & Thermodynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Xiang,Deng, Yuehua,Lu, Changyu,et al. Organic Base-Catalyzed C-S Bond Construction from CO2: A New Route for the Synthesis of Benzothiazolones[J]. CATALYSTS,2018,8(7). |
| APA | Gao, Xiang,Deng, Yuehua,Lu, Changyu,Zhang, Lei,Wang, Xintao,&Yu, Bo.(2018).Organic Base-Catalyzed C-S Bond Construction from CO2: A New Route for the Synthesis of Benzothiazolones.CATALYSTS,8(7). |
| MLA | Gao, Xiang,et al."Organic Base-Catalyzed C-S Bond Construction from CO2: A New Route for the Synthesis of Benzothiazolones".CATALYSTS 8.7(2018). |
入库方式： OAI收割
来源：化学研究所
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