A turn-on fluorescent sensor for zinc and cadmium ions based on perylene tetracarboxylic diimide
文献类型：期刊论文
| 作者 | Liu, Xiangjun1; Zhang, Nan1,2; Zhou, Jin1,2; Chang, Tianjun1,2; Fang, Canliang1,2; Shangguan, Dihua1 |
| 刊名 | ANALYST
 |
| 出版日期 | 2013 |
| 卷号 | 138期号:3页码:901-906 |
| ISSN号 | 0003-2654 |
| DOI | 10.1039/c2an36203a |
| 英文摘要 | In this paper, we describe a turn-on fluorescent probe for Zn2+ and Cd2+ ion detection and discrimination. This probe, N'-bis-(N, N-di-(2-pyridylmethyl)-ethane-1,2-diamine)-perylene-3,4,9,10-tetracarboxylic-diimide (PDI-DIDPA), exhibits very low fluorescence at pH above 6.0 due to the photo-induced electron transfer (PET) process from 2-pyridylmethyl-amine (DPA) to perylene tetracarboxylic diimide (PDI). Zn2+ and Cd2+ can chelate PDI-DIDPA to form a stable complex at pH 6.0-7.0 and 9.0 respectively, and inhibit the PET process, which result in the fluorescence recovery of PDI-DIDPA. This fluorescence turn-on behavior allows the detection of Zn2+ in the range of 0.1-4.0 mu M and Cd2+ in the range of 0.1-5.0 mu M. The limit of detection for Zn2+ and Cd2+ is as low as 32 nM and 48 nM. The high selectivity, high sensitivity and easy operation make this probe suitable for the rapid detection of Zn2+ and Cd2+ respectively. The different response of PDI-DIDPA to Zn2+ and Cd2+ at different pH makes it possible to discriminate Zn2+ and Cd2+ by simply adjusting the pH of the working solution. |
| 语种 | 英语 |
| WOS记录号 | WOS:000312944400026 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41994]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shangguan, Dihua |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Analyt Chem Living Biosyst, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiangjun,Zhang, Nan,Zhou, Jin,et al. A turn-on fluorescent sensor for zinc and cadmium ions based on perylene tetracarboxylic diimide[J]. ANALYST,2013,138(3):901-906. |
| APA | Liu, Xiangjun,Zhang, Nan,Zhou, Jin,Chang, Tianjun,Fang, Canliang,&Shangguan, Dihua.(2013).A turn-on fluorescent sensor for zinc and cadmium ions based on perylene tetracarboxylic diimide.ANALYST,138(3),901-906. |
| MLA | Liu, Xiangjun,et al."A turn-on fluorescent sensor for zinc and cadmium ions based on perylene tetracarboxylic diimide".ANALYST 138.3(2013):901-906. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。