Enhanced working temperature of PEO-based polymer electrolyte via porous PTFE film as an efficient heat resister
文献类型：期刊论文
| 作者 | Wu, Xing-Long1,2; Li, Yan-Hua1,2; Wu, Na1,2; Xin, Sen1,2; Kim, Jee-Hoon3; Yan, Yang1,2; Lee, Jong-Sook3; Guo, Yu-Guo1,2
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| 刊名 | SOLID STATE IONICS
 |
| 出版日期 | 2013-09-01 |
| 卷号 | 245页码:1-7 |
| 关键词 | Polymer Electrolytes Ionic Conductivity Polytetrafluoroethene Polyethylene Oxide Lithium-ion Batteries |
| ISSN号 | 0167-2738 |
| DOI | 10.1016/j.ssi.2013.05.012 |
| 英文摘要 | Porous polytetrafluoroethylene (PTFE) films have been used as heat resisters to increase the working temperature of traditional polyethylene oxide (PEO)-based polymer electrolytes. Two composite polymer electrolytes (CPEs), including lithium bis(oxalate)borate-succinonitrile-polyethylene oxide-polytetrafluoroethene (LiBOB-SN-PEO-PTFE) and lithium trifluoromethanesulfonate-polyethylene oxide-polytetrafluoroethene (LiCF3SO3-PEO-PTFE) have been prepared by introducing corresponding PEO-based electrolytes into the pores of PTFE films, and investigated by scanning electron microscope, X-ray diffraction, differential scanning calorimetry and electrochemical impedance spectroscopy. It is found that the porous PTFE films play an important role in increasing the working temperature of CPEs (up to 180 degrees C), which is much higher than that of traditional PEO-based CPEs (ca. 100 degrees C). Furthermore, the as-prepared CPEs also exhibit outstanding high-temperature stability (up to 120 h) and high ionic conductivities of about 4.20 and 0.97 mS cm(-1) at 160 degrees C for LiBOB-SN-PEO-PTFE and LiCF3SO3-PEO-PTFE CPEs, respectively, promising a possible long-term service life for high-temperature lithium-ion batteries. (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322559600001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42012]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo, Yu-Guo |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Mol Nanostruct & Nanotechnol, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chonnam Natl Univ WCU, Sch Mat Sci & Engn, Kwangju 500757, South Korea |
| 推荐引用方式 GB/T 7714 | Wu, Xing-Long,Li, Yan-Hua,Wu, Na,et al. Enhanced working temperature of PEO-based polymer electrolyte via porous PTFE film as an efficient heat resister[J]. SOLID STATE IONICS,2013,245:1-7. |
| APA | Wu, Xing-Long.,Li, Yan-Hua.,Wu, Na.,Xin, Sen.,Kim, Jee-Hoon.,...&Guo, Yu-Guo.(2013).Enhanced working temperature of PEO-based polymer electrolyte via porous PTFE film as an efficient heat resister.SOLID STATE IONICS,245,1-7. |
| MLA | Wu, Xing-Long,et al."Enhanced working temperature of PEO-based polymer electrolyte via porous PTFE film as an efficient heat resister".SOLID STATE IONICS 245(2013):1-7. |
入库方式： OAI收割
来源：化学研究所
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