BETS3[Cu-2(C2O4)(3)](CH3OH)(2): an organic-inorganic hybrid antiferromagnetic metal (BETS = bisethylene(tetraselenfulvalene))
文献类型：期刊论文
| 作者 | Zhang, Bin1,2; Zhang, Yan3; Wang, Zheming4; Gao, Song4; Guo, Yanjun5; Liu, Fen2,6; Zhu, Daoben1,2 |
| 刊名 | CRYSTENGCOMM
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:18页码:3529-3535 |
| ISSN号 | 1466-8033 |
| DOI | 10.1039/c2ce26552d |
| 英文摘要 | The organic-inorganic hybrid charge-transfer salt of BETS and a two-dimensional oxalate-metalate: BETS3[Cu-2(C2O4)(3)](CH3OH)(2) (1) was obtained by the electrochemical oxidation of neutral BETS in the presence of [(C2H5)(3)NH](2)Cu(C2O4)(2) in a C6H5Cl-CH3OH solution. 1 crystallizes in a triclinic crystal system with cell parameters: a = 8.7716(3) angstrom, b = 16.9903(6) angstrom, c = 20.5716(7) angstrom, alpha = 104.794(2)degrees,beta = 102.209(2)degrees, gamma = 92.243(2)degrees, V = 2883.1(2) angstrom(3) and P1 in 293 K. Donor layers and Jahn-Teller distorted honeycomb anions stack alternatively along the c axis in 1. The crystal structure of 1 is similar to the reported compound [BEDT-TTF](3)[Cu-2(C2O4)(3)](CH3OH)(2) (BEDT-TTF = bis(ethylene-dithio) tetrathiafulvalene, ET). Compared with the BEDT-TTF salt, the c axis expands by 2.3% at room temperature, the shorter interaction between the donor molecules increases, the room temperature conductivity increases from 4 S cm(-1) to 140 S cm(-1) and the antiferromagnetic interaction between the metal atoms with Jahn-Teller distortion through the oxalato-bridge enhances. |
| 语种 | 英语 |
| WOS记录号 | WOS:000317594600005 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42020]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Bin |
| 作者单位 | 1.Chinese Acad Sci, Organ Solid Lab, BNLMS, CMS, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Peking Univ, Dept Phys, Beijing 100871, Peoples R China 4.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 5.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China 6.Chinese Acad Sci, CMS, Ctr Physiochem Anal & Measurement, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Bin,Zhang, Yan,Wang, Zheming,et al. BETS3[Cu-2(C2O4)(3)](CH3OH)(2): an organic-inorganic hybrid antiferromagnetic metal (BETS = bisethylene(tetraselenfulvalene))[J]. CRYSTENGCOMM,2013,15(18):3529-3535. |
| APA | Zhang, Bin.,Zhang, Yan.,Wang, Zheming.,Gao, Song.,Guo, Yanjun.,...&Zhu, Daoben.(2013).BETS3[Cu-2(C2O4)(3)](CH3OH)(2): an organic-inorganic hybrid antiferromagnetic metal (BETS = bisethylene(tetraselenfulvalene)).CRYSTENGCOMM,15(18),3529-3535. |
| MLA | Zhang, Bin,et al."BETS3[Cu-2(C2O4)(3)](CH3OH)(2): an organic-inorganic hybrid antiferromagnetic metal (BETS = bisethylene(tetraselenfulvalene))".CRYSTENGCOMM 15.18(2013):3529-3535. |
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来源：化学研究所
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