Biomimetic preparation and multi-scale microstructures of nano-silica/polyurethane elastomeric fibers
文献类型:期刊论文
作者 | Liu, Quanyong1; Gao, Li1; Jiang, Lei1,2 |
刊名 | PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
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出版日期 | 2013-12-01 |
卷号 | 23期号:6页码:532-542 |
关键词 | Biomimetic Preparation Elastomeric Fiber Nano-silica Polyurethane Microstructure Self-assembly |
ISSN号 | 1002-0071 |
DOI | 10.1016/j.pnsc.2013.12.001 |
英文摘要 | Bioinspired by the spinning of spider silks, the biomimetic preparation of nano-sdica/polyurethme (nano-SiO2TTPU) efastomeric fibers with distinctive imulti-scale microstructures was successfully implemented. The formation mechanism of the nano-SiO2/TPU fibers was considered as the integrated mechanism of diffusion, coagulation, self-assembly, and microphase separation, same as that of the native spider silks. The mass ratio of nano-SiO2 to TPU,t ffeady influenced the external and inner microstnictures of the nano-Si02/TPU fibers. The formation process of the nano-SiO2/TPU fibers was simply described as three main stages, and the second stage, such as the adding of the ethanol solvents and nano-SiO2 in different diameters, was thought to be very crucial for the final external and inner microstructures of the prepared fibers. For example, the adding of the ethanol and the nano-SiO2 spheres in diameter of 10 nin resufted in the existence of many TPU-self-asserribled imicrospheres mostly spaced apart by the nano-SiO2 aggregates in the nano-SiO2/TPU fibers, white the adding of die ethanol and the nano-SiO2 spheres in diameter of 100 am resulted in the existence of the nano-SiO2 spheres, instead of the TPU-seffassembled miciuspheres, distributed in the nano-SiO2/TPU fibers. (C) 2013 Chinese Materials Research Society. Production and hosting by Elsevier All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000330045600003 |
出版者 | ELSEVIER SCIENCE INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/42037] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Quanyong |
作者单位 | 1.Beihang Univ, Sch Chem & Environm,Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing Key Lab Bioinspired Energy Mat & Devices, Beijing 100191, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci MNLMS, Key Lab Organ Solids, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Quanyong,Gao, Li,Jiang, Lei. Biomimetic preparation and multi-scale microstructures of nano-silica/polyurethane elastomeric fibers[J]. PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL,2013,23(6):532-542. |
APA | Liu, Quanyong,Gao, Li,&Jiang, Lei.(2013).Biomimetic preparation and multi-scale microstructures of nano-silica/polyurethane elastomeric fibers.PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL,23(6),532-542. |
MLA | Liu, Quanyong,et al."Biomimetic preparation and multi-scale microstructures of nano-silica/polyurethane elastomeric fibers".PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL 23.6(2013):532-542. |
入库方式: OAI收割
来源:化学研究所
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