Synthesis, structure, optoelectronic properties of novel zinc Schiff-base complexes
文献类型:期刊论文
作者 | Wang LiPing1; Jiao ShiBo1; Zhang WeiFeng2; Liu YunQi2; Yu Gui2 |
刊名 | CHINESE SCIENCE BULLETIN
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出版日期 | 2013-08-01 |
卷号 | 58期号:22页码:2733-2740 |
关键词 | Zinc Complexes Schiff-base Ligands Electroluminescence |
ISSN号 | 1001-6538 |
DOI | 10.1007/s11434-013-5786-2 |
英文摘要 | Two novel zinc Schiff-base complexes, bis-(N-(2-hydroxybenzidene)-p-aminodimethylaniline)zinc(II) (2) and bis-(N-(2-hydroxy-1-naphthidene)-p-aminodimethylaniline)zinc(II) (4) were designed and synthesized. Both the complexes exhibit good solubility in organic solvents and excellent thermal stabilities. A single crystal of 2 was grown and its crystalline structure was determined from X-ray diffraction data. Analysis of the electronic structures of both the zinc complexes calculated by density functional theory reveals a localization of orbital. The UV-Vis absorption and photoluminescence profiles of 4 in thin film are similar to those of 2, but the emission for 4 is red-shifted compared to 2. Three-layered devices with a configuration of ITO/NPB/2/Alq(3)/LiF/Al and ITO/NPB/4/Alq(3)/LiF/Al show a yellow and red emission, respectively. |
语种 | 英语 |
WOS记录号 | WOS:000323342300010 |
出版者 | SCIENCE PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/42051] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang LiPing |
作者单位 | 1.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wang LiPing,Jiao ShiBo,Zhang WeiFeng,et al. Synthesis, structure, optoelectronic properties of novel zinc Schiff-base complexes[J]. CHINESE SCIENCE BULLETIN,2013,58(22):2733-2740. |
APA | Wang LiPing,Jiao ShiBo,Zhang WeiFeng,Liu YunQi,&Yu Gui.(2013).Synthesis, structure, optoelectronic properties of novel zinc Schiff-base complexes.CHINESE SCIENCE BULLETIN,58(22),2733-2740. |
MLA | Wang LiPing,et al."Synthesis, structure, optoelectronic properties of novel zinc Schiff-base complexes".CHINESE SCIENCE BULLETIN 58.22(2013):2733-2740. |
入库方式: OAI收割
来源:化学研究所
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