Crystallization and Tensile Behavior of Poly(L-lactide)/Poly(ethylene oxide) Blend
文献类型:期刊论文
作者 | Xiong Zu-Jiang1; Zhang Xiu-Qin2; Liu Guo-Ming1; Zhao Ying1; Wang Rui2; Wang Du-Jin1 |
刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
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出版日期 | 2013-05-10 |
卷号 | 34期号:5页码:1288-1294 |
关键词 | Poly(L-lactic Acid) Ultra High Molecular Weight Poly(Ethylene Oxide) Stretching Behavior Crystallization |
ISSN号 | 0251-0790 |
DOI | 10.7503/cjcu20120925 |
英文摘要 | Poly(L-lactic acid) (PLLA) and PLLA/ultra high molecular weight poly (ethylene oxide) (PEO) blend were prepared by melt-mixing, respectively. The morphology and the stretching behavior as well as their dependence on stretching temperatures of PLLA and PLLA/PEO blend were studied with a combination of differential scanning calorimetry(DSC), scanning electron microscopy(SEM), and in-situ synchrotron wide-angle X-ray scattering(WAXS). The PLLA/PEO blend exhibited phase-separated morphology, with PEO particles as dispersed phase evenly distributed in PLLA matrix. The addition of PEO remarkably decreases the glass transition temperature(T-g) and increases the crystallization rate of PLLA. The fracture strain of PLLA/PEO blend increases drastically under uniaxial stretching at different temperatures of 25-60 degrees C. At lower stretching temperature (60 degrees C), the crystallization rate and fracture strain of PLLA/PEO blend increase. At higher stretching temperature (80 degrees C), the fracture stain of the blend is lower than that of the pure PLLA, while the crystallization rate is still higher than that of PLLA. |
语种 | 英语 |
WOS记录号 | WOS:000319546600042 |
出版者 | HIGHER EDUCATION PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/42091] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhang Xiu-Qin |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Beijing Inst Fash Technol, Beijing Key Lab Clothing Mat R&D & Assessment, Sch Mat Sci & Engn, Beijing 100029, Peoples R China |
推荐引用方式 GB/T 7714 | Xiong Zu-Jiang,Zhang Xiu-Qin,Liu Guo-Ming,et al. Crystallization and Tensile Behavior of Poly(L-lactide)/Poly(ethylene oxide) Blend[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2013,34(5):1288-1294. |
APA | Xiong Zu-Jiang,Zhang Xiu-Qin,Liu Guo-Ming,Zhao Ying,Wang Rui,&Wang Du-Jin.(2013).Crystallization and Tensile Behavior of Poly(L-lactide)/Poly(ethylene oxide) Blend.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,34(5),1288-1294. |
MLA | Xiong Zu-Jiang,et al."Crystallization and Tensile Behavior of Poly(L-lactide)/Poly(ethylene oxide) Blend".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 34.5(2013):1288-1294. |
入库方式: OAI收割
来源:化学研究所
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