Synthesis and Photophysical Properties of Doubly beta-to-beta Bridged Cyclic Zn-II Porphyrin Arrays
文献类型：期刊论文
| 作者 | Hao, Qingshan1; Zeng, Yi1; Yu, Tianjun1; Chen, Jinping1; Yang, Guoqiang2; Li, Yi1 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2013-05-01 |
| 卷号 | 8期号:5页码:1015-1022 |
| 关键词 | Conjugation Cross-coupling Macrocycles Porphyrinoids Two-photon Absorption |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201300035 |
| 英文摘要 | A series of doubly -to- bridged cyclic ZnII porphyrin arrays were prepared by a stepwise SuzukiMiyaura coupling reaction of borylated ZnII porphyrin with different bridge groups. The coupling of the building block of ,-diboryl ZnII porphyrin with different bridges provided the doubly -to- carbazole-bridged ZnII porphyrin array , the fluorene-bridged ZnII porphyrin array , the fluorenone-bridged ZnII porphyrin array , and the three-carbazole-bridged ZnII porphyrin ring . The structural assignment of was confirmed by the X-ray diffraction analysis, which revealed a highly symmetrical and remarkably bent syn-form structure. The incorporation of bridge units with different electronic effects results in different photophysical properties of the cyclic ZnII porphyrin arrays. Comprehensive photophysical studies demonstrate that the electron-withdrawing bridge fluorenone has the largest electronic interaction with the ZnII porphyrin unit among the series, thus resulting in the highest two-photon absorption cross-section values (sigma(2)) of 6570 +/- 60GM for . The present work provides a new strategy for developing porphyrin-based optical materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000318235400023 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42096]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Jinping |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 2.Chinese Acad Sci, BNLMS, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hao, Qingshan,Zeng, Yi,Yu, Tianjun,et al. Synthesis and Photophysical Properties of Doubly beta-to-beta Bridged Cyclic Zn-II Porphyrin Arrays[J]. CHEMISTRY-AN ASIAN JOURNAL,2013,8(5):1015-1022. |
| APA | Hao, Qingshan,Zeng, Yi,Yu, Tianjun,Chen, Jinping,Yang, Guoqiang,&Li, Yi.(2013).Synthesis and Photophysical Properties of Doubly beta-to-beta Bridged Cyclic Zn-II Porphyrin Arrays.CHEMISTRY-AN ASIAN JOURNAL,8(5),1015-1022. |
| MLA | Hao, Qingshan,et al."Synthesis and Photophysical Properties of Doubly beta-to-beta Bridged Cyclic Zn-II Porphyrin Arrays".CHEMISTRY-AN ASIAN JOURNAL 8.5(2013):1015-1022. |
入库方式： OAI收割
来源：化学研究所
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