Solution Effect on Diazonium-Modified Au(111): Reactions and Structures
文献类型：期刊论文
| 作者 | Cui, Bo1,2; Gu, Jing-Ying1,2; Chen, Ting1; Yan, Hui-Juan1; Wang, Dong1; Wan, Li-Jun1 |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2013-03-05 |
| 卷号 | 29期号:9页码:2955-2960 |
| ISSN号 | 0743-7463 |
| DOI | 10.1021/la400185e |
| 英文摘要 | Surface modifications of a Au(111) electrode with 4-bromobenzenediazonium tetrafluoroborate (BBD) in acetonitrile (ACN) and 0.1 M HClO4 have been characterized by scanning tunneling microscopy (STM). In ACN, STM results reveal the formation of disordered thin organic films. The involvement of the radical as an intermediate is evidenced by the negative effect of radical scavengers on organic thin film formation. In contrast, the 4,4'-dibromobiphenyl monolayer is observed when the aqueous solution is used as a medium to carry out the grafting experiment. The biphenyl compound is considered to be generated by a radical-radical coupling reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000315844100019 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42101]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Bo,Gu, Jing-Ying,Chen, Ting,et al. Solution Effect on Diazonium-Modified Au(111): Reactions and Structures[J]. LANGMUIR,2013,29(9):2955-2960. |
| APA | Cui, Bo,Gu, Jing-Ying,Chen, Ting,Yan, Hui-Juan,Wang, Dong,&Wan, Li-Jun.(2013).Solution Effect on Diazonium-Modified Au(111): Reactions and Structures.LANGMUIR,29(9),2955-2960. |
| MLA | Cui, Bo,et al."Solution Effect on Diazonium-Modified Au(111): Reactions and Structures".LANGMUIR 29.9(2013):2955-2960. |
入库方式： OAI收割
来源：化学研究所
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