Enhanced photocatalytic hydrogen evolution based on efficient electron transfer in triphenylamine-based dye functionalized Au@Pt bimetallic core/shell nanocomposite
文献类型：期刊论文
| 作者 | Cheng, Manhuan1,2; Zhu, Mingshan3; Du, Yukou1; Yang, Ping1 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2013-07-17 |
| 卷号 | 38期号:21页码:8631-8638 |
| 关键词 | Au@pt Bimetallic Core/shell Nanocomposite Triphenylamine Derivative Dye Electron Transfer Homogeneous Photocatalysis Hydrogen Evolution |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2013.05.040 |
| 英文摘要 | An efficient photocatalytic hydrogen evolution system based on triphenylamine-based dye functionalized bimetallic Au@Pt core/shell nanocomposite (Au@Pt-TPAD) was reported. Transmission electron microscopy (TEM), X-ray diffraction (XRD) and UV-vis absorption spectra suggested that Au@Pt-TPAD nanocomposite consisted of a bimetallic nanoparticle with Au core and Pt shell nanostructure. The photoelectrochemical result suggested that photoinduced electrons could efficiently transfer from the triphenylamine derivative molecules to the bimetallic nanoparticles. Photocatalytic results showed that the Au@Pt(2-)TPAD bimetallic nanocomposite could be used as a stable photoinduced H-2 evolution photocatalyst. Compared with the monometallic counterpart (Au-TPAD or Pt-TPAD), the bimetallic nanocomposite showed much higher catalytic activity for the photocatalytic hydrogen evolution. The amount of hydrogen evolution on the optimal catalyst under 12 h UV-vis light irradiation was about 37.5 mu mol. The enhancement of the photocatalytic activity might be attributed to the synergistic effect between the two metals in bimetallic nanoparticles with core/shell structure. This investigation might open up new opportunities for the development of dye functionalized heterometallic nanocomposite with enhanced photocatalytic performance. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322052800004 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42126]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Ping |
| 作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China 2.Huangshan Univ, Modern Educ Technol Ctr, Huangshan 245041, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Manhuan,Zhu, Mingshan,Du, Yukou,et al. Enhanced photocatalytic hydrogen evolution based on efficient electron transfer in triphenylamine-based dye functionalized Au@Pt bimetallic core/shell nanocomposite[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2013,38(21):8631-8638. |
| APA | Cheng, Manhuan,Zhu, Mingshan,Du, Yukou,&Yang, Ping.(2013).Enhanced photocatalytic hydrogen evolution based on efficient electron transfer in triphenylamine-based dye functionalized Au@Pt bimetallic core/shell nanocomposite.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,38(21),8631-8638. |
| MLA | Cheng, Manhuan,et al."Enhanced photocatalytic hydrogen evolution based on efficient electron transfer in triphenylamine-based dye functionalized Au@Pt bimetallic core/shell nanocomposite".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38.21(2013):8631-8638. |
入库方式： OAI收割
来源：化学研究所
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