From Nitro- to Sulfonyl-Based Chromophores: Improvement of the Comprehensive Performance of Nonlinear Optical Dendrimers
文献类型：期刊论文
| 作者 | Wu, Wenbo1; Xu, Guohua2; Li, Conggang2; Yu, Gui3; Liu, Yunqi3; Ye, Cheng3; Qin, Jingui1; Li, Zhen1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2013-05-01 |
| 卷号 | 19期号:21页码:6874-6888 |
| 关键词 | Click Chemistry Chromophores Dendrimers Nonlinear Optics Sulfonyl |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201203567 |
| 英文摘要 | Through the combination of the divergent and convergent approaches, coupled with the utilization of the powerful Sharpless click-chemistry reaction, two series of sulfonyl-based high-generation NLO dendrimers were conveniently prepared with high purity and in satisfactory yields. Thanks to the perfect three-dimensional (3D) spatial isolation from the highly branched structure and the isolation effect of the exterior benzene moieties and the interior triazole rings, these dendrimers exhibited large second harmonic generation coefficient (d33) values up to 181pmV1, which, to the best of our knowledge, is the highest value so far for polymers containing sulfonyl-based chromophore moieties. Meanwhile, compared with the nitro-chromophore-based analogues, their optical transparency and NLO stability were improved in a large degree, due to the lower dipole moment () and the special main-chain structure of sulfonyl-based chromophore in these dendrimers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000318923800040 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42147]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Conggang |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, China State Key Lab Magnet Resonance & Atom & Mol, Wuhan 430071, Peoples R China 3.Chinese Acad Sci, Inst Chem, Organ Solids Labs, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Wenbo,Xu, Guohua,Li, Conggang,et al. From Nitro- to Sulfonyl-Based Chromophores: Improvement of the Comprehensive Performance of Nonlinear Optical Dendrimers[J]. CHEMISTRY-A EUROPEAN JOURNAL,2013,19(21):6874-6888. |
| APA | Wu, Wenbo.,Xu, Guohua.,Li, Conggang.,Yu, Gui.,Liu, Yunqi.,...&Li, Zhen.(2013).From Nitro- to Sulfonyl-Based Chromophores: Improvement of the Comprehensive Performance of Nonlinear Optical Dendrimers.CHEMISTRY-A EUROPEAN JOURNAL,19(21),6874-6888. |
| MLA | Wu, Wenbo,et al."From Nitro- to Sulfonyl-Based Chromophores: Improvement of the Comprehensive Performance of Nonlinear Optical Dendrimers".CHEMISTRY-A EUROPEAN JOURNAL 19.21(2013):6874-6888. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。