Chain packing and phase transition of N-hexacosylated polyethyleneimine comb-like polymer: A combined investigation by synchrotron X-ray scattering and FTIR spectroscopy
文献类型：期刊论文
| 作者 | Shi, Haifeng1; Wang, Haixia1; Yin, Yiping1; Liu, Guoming2; Zhang, Xingxiang1; Wang, Dujin2 |
| 刊名 | POLYMER
 |
| 出版日期 | 2013-10-18 |
| 卷号 | 54期号:22页码:6261-6266 |
| 关键词 | Comb-like Polymer Phase Transition Metastable Structure |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2013.09.024 |
| 英文摘要 | In this paper, the chain packing and phase transition of comb-like polymer has been deeply analyzed with N-hexacosylated polyethyleneimine (PEI26C) as a template, fabricated through the reaction between n-hexacosyl bromide and PEI in a homogenous solution. The effect of long alkyl groups on the chain packing and phase transition of PEI26C was systematically investigated by synchrotron X-ray scattering and variable-temperature FTIR spectroscopy. PEI26C comb-like polymer exhibited an interesting structure-evolution process, and phase transformation from orthorhombic (beta(O)), monoclinic (beta(M)), to hexagonal (alpha(H)) phase, and finally to amorphous state was demonstrated, indicating that large alkyl domains induced the complicated structures. Size-depended phase transition behavior provides an insight into the formation of metastable structure during the early stage of polymer crystallization. (C) 2013 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000326140700026 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42159]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Haifeng |
| 作者单位 | 1.Tianjin Polytech Univ, Inst Funct Fibers, Tianjin Municipal Key Lab Fiber Modificat & Funct, State Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300387, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Haifeng,Wang, Haixia,Yin, Yiping,et al. Chain packing and phase transition of N-hexacosylated polyethyleneimine comb-like polymer: A combined investigation by synchrotron X-ray scattering and FTIR spectroscopy[J]. POLYMER,2013,54(22):6261-6266. |
| APA | Shi, Haifeng,Wang, Haixia,Yin, Yiping,Liu, Guoming,Zhang, Xingxiang,&Wang, Dujin.(2013).Chain packing and phase transition of N-hexacosylated polyethyleneimine comb-like polymer: A combined investigation by synchrotron X-ray scattering and FTIR spectroscopy.POLYMER,54(22),6261-6266. |
| MLA | Shi, Haifeng,et al."Chain packing and phase transition of N-hexacosylated polyethyleneimine comb-like polymer: A combined investigation by synchrotron X-ray scattering and FTIR spectroscopy".POLYMER 54.22(2013):6261-6266. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。