Ethylene Polymerization Using (Imino) vanadium(V) Dichloride Complexes Containing (Anilido) methyl-pyridine, -quinoline Ligands-Halogenated Al Alkyls Catalyst Systems
文献类型：期刊论文
| 作者 | Igarashi, Atsushi1; Zhang, Wenjuan2; Sun, Wen-Hua2 ; Nomura, Kotohiro1
|
| 刊名 | CATALYSTS
 |
| 出版日期 | 2013-03-01 |
| 卷号 | 3期号:1页码:148-156 |
| 关键词 | Ethylene Vanadium Catalysts Polymerization Ligand Effect |
| ISSN号 | 2073-4344 |
| DOI | 10.3390/catal3010148 |
| 英文摘要 | The effect of ligand and Al cocatalysts in ethylene polymerization, using V(N-1-adamantyl)Cl-2(L) [L = 2-(2,6-Me2C6H3) NCH2(C9H6N), 8-(2,6-Me2C6H3) NCH2(C9H6N)] and V(N-2-MeC6H3) Cl-2[2-(2,6-R'2C6H3) NCH2(C5H4N)] (R' = Me, Pr-i), has been explored. The reaction products in the presence of Et2AlCl or Me2AlCl cocatalyst were polyethylene whereas the reaction product of the 2-methylphenylimido analogues in the presence of MAO cocatalyst was 1-butene with high selectivity, suggesting that the catalyst/cocatalyst nuclearity effect plays a role in this catalysis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000339585000010 |
| 出版者 | MDPI AG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42180]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Nomura, Kotohiro |
| 作者单位 | 1.Tokyo Metropolitan Univ, Dept Chem, Hachioji, Tokyo 1920397, Japan 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Igarashi, Atsushi,Zhang, Wenjuan,Sun, Wen-Hua,et al. Ethylene Polymerization Using (Imino) vanadium(V) Dichloride Complexes Containing (Anilido) methyl-pyridine, -quinoline Ligands-Halogenated Al Alkyls Catalyst Systems[J]. CATALYSTS,2013,3(1):148-156. |
| APA | Igarashi, Atsushi,Zhang, Wenjuan,Sun, Wen-Hua,&Nomura, Kotohiro.(2013).Ethylene Polymerization Using (Imino) vanadium(V) Dichloride Complexes Containing (Anilido) methyl-pyridine, -quinoline Ligands-Halogenated Al Alkyls Catalyst Systems.CATALYSTS,3(1),148-156. |
| MLA | Igarashi, Atsushi,et al."Ethylene Polymerization Using (Imino) vanadium(V) Dichloride Complexes Containing (Anilido) methyl-pyridine, -quinoline Ligands-Halogenated Al Alkyls Catalyst Systems".CATALYSTS 3.1(2013):148-156. |
入库方式： OAI收割
来源：化学研究所
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