Main-chain second-order nonlinear optical polyaryleneethynylenes containing isolation chromophores: enhanced nonlinear optical properties, improved optical transparency and stability
文献类型：期刊论文
| 作者 | Wu, Wenbo1; Xin, Shaohui1; Xu, Zhen1; Ye, Cheng2; Qin, Jingui1; Li, Zhen1 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2013 |
| 卷号 | 4期号:11页码:3196-3203 |
| ISSN号 | 1759-9954 |
| DOI | 10.1039/c3py00257h |
| 英文摘要 | In this paper, five nitro azo chromophore based main-chain second-order nonlinear optical (NLO) polyaryleneethynylenes are successfully prepared, in which isolation chromophore moieties (sulfonyl ones) with different concentrations were introduced to improve the poling efficiency of the resultant polymers. Thanks to the effect of the isolation chromophore, P5 exhibited the largest d(33) value of 111.1 pm V-1 as well as the best thermal stability and optical transparency, indicating that the isolation chromophore moieties could alleviate the "nonlinearity-stability trade off" and "nonlinearity-transparency trade off" in the NLO area efficiently. |
| 语种 | 英语 |
| WOS记录号 | WOS:000318557600005 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42208]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zhen |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Wenbo,Xin, Shaohui,Xu, Zhen,et al. Main-chain second-order nonlinear optical polyaryleneethynylenes containing isolation chromophores: enhanced nonlinear optical properties, improved optical transparency and stability[J]. POLYMER CHEMISTRY,2013,4(11):3196-3203. |
| APA | Wu, Wenbo,Xin, Shaohui,Xu, Zhen,Ye, Cheng,Qin, Jingui,&Li, Zhen.(2013).Main-chain second-order nonlinear optical polyaryleneethynylenes containing isolation chromophores: enhanced nonlinear optical properties, improved optical transparency and stability.POLYMER CHEMISTRY,4(11),3196-3203. |
| MLA | Wu, Wenbo,et al."Main-chain second-order nonlinear optical polyaryleneethynylenes containing isolation chromophores: enhanced nonlinear optical properties, improved optical transparency and stability".POLYMER CHEMISTRY 4.11(2013):3196-3203. |
入库方式： OAI收割
来源：化学研究所
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