Electronic Structure of Graphdiyne Probed by X-ray Absorption Spectroscopy and Scanning Transmission X-ray Microscopy
文献类型：期刊论文
| 作者 | Zhong, Jun1,2; Wang, Jian3; Zhou, Ji-Gang3; Mao, Bao-Hua1,2; Liu, Chang-Hai1,2; Liu, Hui-Biao4; Li, Yu-Liang4; Sham, Tsun-Kong1,3,5; Sun, Xu-Hui1,2; Wang, Sui-Dong1,2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2013-03-21 |
| 卷号 | 117期号:11页码:5931-5936 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/jp310013z |
| 英文摘要 | The electronic structure of graphdiyne exposed to air is investigated utilizing X-ray absorption spectroscopy and scanning transmission X-ray microscopy. It is found that carbon-carbon triple bonds at defect sites in graphdiyne have been changed to double bonds after 3 months in air. The experimental results reveal the existence of oxygen and nitrogen functional groups and indicate that the oxidation takes place throughout the aged graphdiyne while the nitrogen contamination is mainly on its surface. Buckling of the aged graphdiyne is observed, resulting from bond length change due to the opening of triple bonds. It is also shown that annealing at a high temperature such as 800 degrees C may remove most of the functional groups in the aged graphdiyne. |
| 语种 | 英语 |
| WOS记录号 | WOS:000316773000048 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42257]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sham, Tsun-Kong |
| 作者单位 | 1.Soochow Univ, Soochow Univ Western Univ, Joint Ctr Synchrotron Radiat Res, Suzhou 215123, Jiangsu, Peoples R China 2.Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China 3.Univ Saskatchewan, Canadian Light Source, Saskatoon, SK S7N 0X4, Canada 4.Chinese Acad Sci, CAS Key Lab Organ Solids, BNLMS, Inst Chem, Beijing 100190, Peoples R China 5.Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada |
| 推荐引用方式 GB/T 7714 | Zhong, Jun,Wang, Jian,Zhou, Ji-Gang,et al. Electronic Structure of Graphdiyne Probed by X-ray Absorption Spectroscopy and Scanning Transmission X-ray Microscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2013,117(11):5931-5936. |
| APA | Zhong, Jun.,Wang, Jian.,Zhou, Ji-Gang.,Mao, Bao-Hua.,Liu, Chang-Hai.,...&Wang, Sui-Dong.(2013).Electronic Structure of Graphdiyne Probed by X-ray Absorption Spectroscopy and Scanning Transmission X-ray Microscopy.JOURNAL OF PHYSICAL CHEMISTRY C,117(11),5931-5936. |
| MLA | Zhong, Jun,et al."Electronic Structure of Graphdiyne Probed by X-ray Absorption Spectroscopy and Scanning Transmission X-ray Microscopy".JOURNAL OF PHYSICAL CHEMISTRY C 117.11(2013):5931-5936. |
入库方式： OAI收割
来源：化学研究所
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