Construction of well-defined butadiynylene-linked perylene bisimide arrays via cross-coupling
文献类型：期刊论文
| 作者 | Kang, Hongwei1,2; Jiang, Wei1; Wang, Zhaohui1 |
| 刊名 | DYES AND PIGMENTS
 |
| 出版日期 | 2013-04-01 |
| 卷号 | 97期号:1页码:244-249 |
| 关键词 | Perylene Bisimide Butadiynylene Linkage Oligomers Hay Coupling Reaction Molecular Wires |
| ISSN号 | 0143-7208 |
| DOI | 10.1016/j.dyepig.2012.12.015 |
| 英文摘要 | A homogeneous series of well-defined oligo-butadiynylene-PBIs have been efficiently synthesized in one pot by Hay Cross-Coupling. It is shocked that the rate of this oxidative coupling reaction is very fast, the whole process just takes a short time no more than 10 s. The four butadiynylene-linked oligomers having good solubility in common solvents show absorption spectra with broad absorption range (from 300 nm to 650 nm) and gradually increasing absorption coefficients (up to 1.4 x 10(5) mol(-1) cm(-1)). From the cyclic voltammentry data, we can see that the LUMO levels are effectively and precisely tuned by embedding butadiynylene linkage between PBI subunits. These compounds are promising for potential applications in molecular electronic devices such as conducting molecular wires and solar cells. (C) 2012 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000315608000034 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42261]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Wei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Hongwei,Jiang, Wei,Wang, Zhaohui. Construction of well-defined butadiynylene-linked perylene bisimide arrays via cross-coupling[J]. DYES AND PIGMENTS,2013,97(1):244-249. |
| APA | Kang, Hongwei,Jiang, Wei,&Wang, Zhaohui.(2013).Construction of well-defined butadiynylene-linked perylene bisimide arrays via cross-coupling.DYES AND PIGMENTS,97(1),244-249. |
| MLA | Kang, Hongwei,et al."Construction of well-defined butadiynylene-linked perylene bisimide arrays via cross-coupling".DYES AND PIGMENTS 97.1(2013):244-249. |
入库方式： OAI收割
来源：化学研究所
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