Manganese-Catalyzed Redox-Neutral C-H Olefination of Ketones with Unactivated Alkenes
文献类型：期刊论文
| 作者 | Hu, Yuanyuan1,2; Zhou, Bingwei1,2; Chen, Hui3; Wang, Congyang1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-09-10 |
| 卷号 | 57期号:37页码:12071-12075 |
| 关键词 | Alkenes C-h Activation Ketones Manganese Olefination |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201806287 |
| 英文摘要 | Since 1987, stoichiometric cyclomanganation of ketones and subsequent reactions with olefins in the presence of either palladium salts or trimethylamine N-oxide (Me3N+O-) have been reported, but the catalytic versions remain untouched so far. Herein, the first manganese-catalyzed redox-neutral C-H olefination of ketones with unactivated alkenes is described, and shows a distinct reactivity with its parent stoichimetric reactions. Remarkably, mechanistic experiments and DFT calculations uncovers a unique concerted bis-metalation deprotonation (CBMD) mechanism of the Mn-Zn-enabled C-H bond activation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000443675700041 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42273]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Hui; Wang, Congyang |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, CAS Res,Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, BNLMS, CAS Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Yuanyuan,Zhou, Bingwei,Chen, Hui,et al. Manganese-Catalyzed Redox-Neutral C-H Olefination of Ketones with Unactivated Alkenes[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(37):12071-12075. |
| APA | Hu, Yuanyuan,Zhou, Bingwei,Chen, Hui,&Wang, Congyang.(2018).Manganese-Catalyzed Redox-Neutral C-H Olefination of Ketones with Unactivated Alkenes.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(37),12071-12075. |
| MLA | Hu, Yuanyuan,et al."Manganese-Catalyzed Redox-Neutral C-H Olefination of Ketones with Unactivated Alkenes".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.37(2018):12071-12075. |
入库方式： OAI收割
来源：化学研究所
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