Synthesis and Reactivity of Metal Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for beta-Alkylation of Secondary Alcohols with Primary Alcohols
文献类型：期刊论文
| 作者 | Shi, Jing1; Hu, Bowen1; Ren, Peng2; Shang, Shu1; Yang, Xinzheng3,4; Chen, Dafa1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2018-08-27 |
| 卷号 | 37期号:16页码:2795-2806 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/acs.organomet.8b00432 |
| 英文摘要 | Three unsymmetrical NNN ligands with a 2-hydroxypyridyl fragment were used to react with RuHCl(PPh3)(3)(CO), affording the three bidentate ruthenium hydride complexes [(R-1-C5H3N-CH2-C5H3N-C5H3N-R-2)RuH(PPh3)(2)(CO)] [Cl] (R-1 = R-2 = OH, 2a; R-1 = OH, R-2 = H, 2b; R-1 = H, R-2 = OH, 2c), respectively. When 2a,b were treated with t-BuOK, the two tridentate products [(O-C5H3N-CH2-C5H3N-C5H3N-R-2)RuH(PPh3)(CO)] (R-2 = OH, 3a; R-2 = H, 3b) were obtained, via selective deprotonation of the -OH group of PyCH2PyOH moiety, indicating that this -OH group is more acidic than that of the PyPyOH moiety. The reaction of 2c with t-BuOK generated the bidentate product [(C5H4N-CH2-C5H3N-C5H3N-O)RuH(PPh3)(2)(CO)] (3c) and the tridentate product [(C5H4N-CH2-C5H3N-C5H3N-O)RuH(PPh3)(CO)] (3d). 3d could be further transformed to the diruthenium complex [(C5H4N-CH-C5H3N-C5H3N-O)Ru(PPh3)(CO)](2) (3e) via C-H activation of the -CH2- group in boiling toluene. The catalytic activity for beta-alkylation of secondary alcohols with primary alcohols of these eight ruthenium complexes was tested, and the bidentate complexes 2c and 3c exhibit the highest activity. Complex 3c can be regarded as the intermediate of 2c. These results are important for developing more efficient bifunctional catalysts for such reactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000443526200017 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42275]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Xinzheng; Chen, Dafa |
| 作者单位 | 1.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China 2.Harbin Inst Technol Shenzhen, Sch Sci, Shenzhen 518055, Peoples R China 3.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem,Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Jing,Hu, Bowen,Ren, Peng,et al. Synthesis and Reactivity of Metal Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for beta-Alkylation of Secondary Alcohols with Primary Alcohols[J]. ORGANOMETALLICS,2018,37(16):2795-2806. |
| APA | Shi, Jing,Hu, Bowen,Ren, Peng,Shang, Shu,Yang, Xinzheng,&Chen, Dafa.(2018).Synthesis and Reactivity of Metal Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for beta-Alkylation of Secondary Alcohols with Primary Alcohols.ORGANOMETALLICS,37(16),2795-2806. |
| MLA | Shi, Jing,et al."Synthesis and Reactivity of Metal Ligand Cooperative Bifunctional Ruthenium Hydride Complexes: Active Catalysts for beta-Alkylation of Secondary Alcohols with Primary Alcohols".ORGANOMETALLICS 37.16(2018):2795-2806. |
入库方式： OAI收割
来源：化学研究所
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