Tuning the Photoinduced Electron Transfer in a Zr-MOF: Toward Solid-State Fluorescent Molecular Switch and Turn-On Sensor
文献类型：期刊论文
| 作者 | Gui, Bo1; Meng, Yi1; Xie, Yang1; Tian, Jianwu2; Yu, Ge1; Zeng, Weixuan1; Zhang, Guanxin2; Gong, Shaolong1; Yang, Chuluo1; Zhang, Deqing2 |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2018-08-23 |
| 卷号 | 30期号:34 |
| 关键词 | Fluorescent Photoinduced Electron Transfer Molecular Switches Solid State Stimuli-responsive Metal-organic Framework Turn-on Sensors |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.201802329 |
| 英文摘要 | The immobilization of fluorescent photoinduced electron transfer (PET) switches/sensors into solid state, which usually cannot maintain their identical properties in solution, has remained a big challenge. Herein, a water-stable anthracene and maleimide appended zirconium-based-metal-organic framework (Zr-MOF; UiO-68-An/Ma) is reported. Unlike the regular intramolecular fluorophore-spacer-receptor format, the separated immobilization of fluorescent (anthracene) and acceptor (maleimide) groups into the framework of a multivariate MOF can also favor a pseudo-intramolecular fluorescent PET process, resulting in UiO-68-An/Ma with very weak fluorescence. Interestingly, after Diels-Alder reaction or thiol-ene reaction of maleimide groups, the pseudo-intramolecular fluorescent PET process in UiO-68-An/Ma fails and the solid-state fluorescence of the crystals is recovered. In addition, UiO-68-An/Ma shows an interesting application as solid-state fluorescent turn-on sensor for biothiols, with the naked eye response at a low concentration of 50 mu mol L-1 within 5 min. This study represents a general strategy to enable the efficient tuning of fluorescent PET switches/sensors in solid state, and considering the fluorescence of the PET-based MOFs can be restored after addition of analyte/target species, this research will definitely inspire to construct stimuli-responsive fluorescent MOFs for interesting applications (e.g., logic gate) in future. |
| 语种 | 英语 |
| WOS记录号 | WOS:000442206400018 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42331]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Deqing; Wang, Cheng |
| 作者单位 | 1.Wuhan Univ, Coll Chem & Mol Sci, Key Lab Biomed Polymers, Minist Educ, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Inst Chem, Organ Solids Lab, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gui, Bo,Meng, Yi,Xie, Yang,et al. Tuning the Photoinduced Electron Transfer in a Zr-MOF: Toward Solid-State Fluorescent Molecular Switch and Turn-On Sensor[J]. ADVANCED MATERIALS,2018,30(34). |
| APA | Gui, Bo.,Meng, Yi.,Xie, Yang.,Tian, Jianwu.,Yu, Ge.,...&Wang, Cheng.(2018).Tuning the Photoinduced Electron Transfer in a Zr-MOF: Toward Solid-State Fluorescent Molecular Switch and Turn-On Sensor.ADVANCED MATERIALS,30(34). |
| MLA | Gui, Bo,et al."Tuning the Photoinduced Electron Transfer in a Zr-MOF: Toward Solid-State Fluorescent Molecular Switch and Turn-On Sensor".ADVANCED MATERIALS 30.34(2018). |
入库方式： OAI收割
来源：化学研究所
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