Nonspherical Liquid Crystalline Assemblies with Programmable Shape Transformation
文献类型：期刊论文
| 作者 | Huo, Meng1,2; Song, Guangjie3,4; Zhang, Jun3,4; Wei, Yen2; Yuan, Jinying1 |
| 刊名 | ACS MACRO LETTERS
 |
| 出版日期 | 2018-08-01 |
| 卷号 | 7期号:8页码:956-961 |
| ISSN号 | 2161-1653 |
| DOI | 10.1021/acsmacrolett.8b00409 |
| 英文摘要 | Liquid crystalline (LC) assemblies with tailored shape and programmable shape transformation were prepared via polymerization-induced self-assembly. The influence of polymerization temperature and solvent on the shape of the LC assemblies indicated that shape of the LC assemblies could be delicately regulated by the repulsive interaction among the solvophilic chains and LC ordering. Programmable shape transformation of ellipsoidal LC assemblies was achieved, taking advantage of the smectic-to-isotropic phase transition. The ellipsoidal assemblies could remain ellipsoids or transform to faceted spheres and spheres, depending on the temperature procedure used. Besides, the generated spheres could be reshaped to ellipsoids with high shape recovery ratio. Small angle X-ray scattering study indicated that the interplay of the reversible smectic-to-isotropic phase transition and kinetic trapping underpins the programmed shape transformation. As a general approach to LC assemblies with programmable shape transformation, our strategy would provide a reliable platform for nanoactuators, nanomotors, and adaptive colloidal devices. |
| 语种 | 英语 |
| WOS记录号 | WOS:000442707200014 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42367]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wei, Yen; Yuan, Jinying |
| 作者单位 | 1.Tsinghua Univ, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 2.Tsinghua Univ, Minist Educ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huo, Meng,Song, Guangjie,Zhang, Jun,et al. Nonspherical Liquid Crystalline Assemblies with Programmable Shape Transformation[J]. ACS MACRO LETTERS,2018,7(8):956-961. |
| APA | Huo, Meng,Song, Guangjie,Zhang, Jun,Wei, Yen,&Yuan, Jinying.(2018).Nonspherical Liquid Crystalline Assemblies with Programmable Shape Transformation.ACS MACRO LETTERS,7(8),956-961. |
| MLA | Huo, Meng,et al."Nonspherical Liquid Crystalline Assemblies with Programmable Shape Transformation".ACS MACRO LETTERS 7.8(2018):956-961. |
入库方式： OAI收割
来源：化学研究所
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