Formation of borata- alkene/ iminium zwitterions by ynamine hydroboration
文献类型：期刊论文
| 作者 | Wang, Long1; Jian, Zhongbao1,2; Daniliuc, Constantin G.1; Kehr, Gerald1; Erker, Gerhard1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2018-08-28 |
| 卷号 | 47期号:32页码:10853-10856 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c8dt02435a |
| 英文摘要 | The ynamine TMP-C?C-CH3 adds HB(C6F5)(2) to give the unsaturated C-2-bridged N/B FLP 5. Compound 5 shows the structural data indicating a marked participation of the zwitterionic mesomeric borata-alkene/iminium form. It splits dihydrogen at r.t. with Z- to E-isomerization at the central C?C double bond. Hydroboration of the ynamine Me3Si-C?C-(NPr2)-Pr-i with HB(C6F5)(2) yields a N/B FLP that shows a strongly distorted central C?C double bond with a rotation of the planes of the substituent pairs at its ends by ca. 57 degrees. |
| 语种 | 英语 |
| WOS记录号 | WOS:000441713000007 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42381]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Erker, Gerhard |
| 作者单位 | 1.Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Renmin St 5625, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Long,Jian, Zhongbao,Daniliuc, Constantin G.,et al. Formation of borata- alkene/ iminium zwitterions by ynamine hydroboration[J]. DALTON TRANSACTIONS,2018,47(32):10853-10856. |
| APA | Wang, Long,Jian, Zhongbao,Daniliuc, Constantin G.,Kehr, Gerald,&Erker, Gerhard.(2018).Formation of borata- alkene/ iminium zwitterions by ynamine hydroboration.DALTON TRANSACTIONS,47(32),10853-10856. |
| MLA | Wang, Long,et al."Formation of borata- alkene/ iminium zwitterions by ynamine hydroboration".DALTON TRANSACTIONS 47.32(2018):10853-10856. |
入库方式： OAI收割
来源：化学研究所
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