Cu-Thienoquinone Charge-Transfer Complex: Synthesis, Characterization, and Application in Organic Transistors
文献类型：期刊论文
| 作者 | Wang, Deliang1,3; Qiao, Xiaolan1; Tao, Jingwei1; Zou, Ye2; Wu, Hongzhuo1,3; Zhu, Daoben2; Li, Hongxiang1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2018-08-08 |
| 卷号 | 10期号:31页码:26451-26455 |
| 关键词 | Charge-transfer Complex Organic Transistor Copper Electrode Doping Layer N-type Organic Transistor Organic Electronics |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.8b08360 |
| 英文摘要 | A facile and unusual reaction between thienoquinone compound QDTBDT2C and copper is reported. The formation of Cu-QDTBDT2C complex is proved by absorption spectra, IR spectra, Raman spectra, and X-ray photoelectron spectroscopy data. This complex can serve as a doping layer at the interface of Cu/QDTBDT2C and greatly improve the performance of organic transistors in which the copper electrode is source/drain electrodes and QDTBDT2C is an active layer. The transistors display an electron mobility of 0.95 cm(2) V-1 s(-1) to our knowledge, the highest electron mobility reported for copper electrode-based n-type transistors and nearly two times higher than that of the Au electrode-based devices. These results demonstrate the potential applications of Cu-QDTBDT2C complex in organic electronics, and the unique properties of QDTBDT2C (spontaneously reacting with copper) provide a new insight into the design of n-type organic semiconductors for copper electrode-based organic transistors. |
| 语种 | 英语 |
| WOS记录号 | WOS:000441477800069 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42439]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Qiao, Xiaolan; Li, Hongxiang |
| 作者单位 | 1.Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem, Key Lab Synthet & Self Assembly Chem Organ Funct, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Deliang,Qiao, Xiaolan,Tao, Jingwei,et al. Cu-Thienoquinone Charge-Transfer Complex: Synthesis, Characterization, and Application in Organic Transistors[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(31):26451-26455. |
| APA | Wang, Deliang.,Qiao, Xiaolan.,Tao, Jingwei.,Zou, Ye.,Wu, Hongzhuo.,...&Li, Hongxiang.(2018).Cu-Thienoquinone Charge-Transfer Complex: Synthesis, Characterization, and Application in Organic Transistors.ACS APPLIED MATERIALS & INTERFACES,10(31),26451-26455. |
| MLA | Wang, Deliang,et al."Cu-Thienoquinone Charge-Transfer Complex: Synthesis, Characterization, and Application in Organic Transistors".ACS APPLIED MATERIALS & INTERFACES 10.31(2018):26451-26455. |
入库方式： OAI收割
来源：化学研究所
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