Insights into the Inhibition of Acidic Hydrolysis of Cellulose by Its Solation
文献类型：期刊论文
| 作者 | Chen, Gongzhe1,2,3; Wang, Xicheng2; Jiang, Yijun2; Mu, Xindong2; Liu, Haichao1 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-08-01 |
| 卷号 | 6期号:8页码:10999-11007 |
| 关键词 | Cellulose Hydrolysis Inhibition Solation |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.8b02418 |
| 英文摘要 | Cellulose hydrolysis in dilute mineral acids was investigated, and a plateau in cellulose conversion was observed such that an extended reaction time did not result in further conversion of cellulose, which severely reduced the hydrolysis efficiency of cellulose. The characterization results indicated that the crystallinity indexes of cellulose and the deposition of humins were not the key factors inhibiting the reaction but rather the solation of cellulose in the presence of water, protons, and anions was the key. The hydrolysis reaction proceeded after the solated state of cellulose was disrupted by means of filtration, increased temperature, or the addition of organic solvents and inorganic salts. However, a new plateau in cellulose conversion eventually formed and inhibited the hydrolysis reaction again. Therefore, continuous disruption of the solated system of cellulose is the key strategy to achieve high cellulose conversion under even mild reaction conditions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000441475500158 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42463]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Mu, Xindong; Liu, Haichao |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Gongzhe,Wang, Xicheng,Jiang, Yijun,et al. Insights into the Inhibition of Acidic Hydrolysis of Cellulose by Its Solation[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(8):10999-11007. |
| APA | Chen, Gongzhe,Wang, Xicheng,Jiang, Yijun,Mu, Xindong,&Liu, Haichao.(2018).Insights into the Inhibition of Acidic Hydrolysis of Cellulose by Its Solation.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(8),10999-11007. |
| MLA | Chen, Gongzhe,et al."Insights into the Inhibition of Acidic Hydrolysis of Cellulose by Its Solation".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.8(2018):10999-11007. |
入库方式： OAI收割
来源：化学研究所
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