Selectively nitrogen-doped carbon materials as superior metal-free catalysts for oxygen reduction
文献类型：期刊论文
| 作者 | Lv, Qing1; Si, Wenyan2; He, Jianjiang1; Sun, Lei3; Zhang, Chunfang4; Wang, Ning1; Yang, Ze1; Li, Xiaodong1; Wang, Xin1; Deng, Weiqiao3,6 |
| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2018-08-23 |
| 卷号 | 9 |
| ISSN号 | 2041-1723 |
| DOI | 10.1038/s41467-018-05878-y |
| 英文摘要 | Doping with pyridinic nitrogen atoms is known as an effective strategy to improve the activity of carbon-based catalysts for the oxygen reduction reaction. However, pyridinic nitrogen atoms prefer to occupy at the edge or defect sites of carbon materials. Here, a carbon framework named as hydrogen-substituted graphdiyne provides a suitable carbon matrix for pyridinic nitrogen doping. In hydrogen-substituted graphdiyne, three of the carbon atoms in a benzene ring are bonded to hydrogen and serve as active sites, like the edge or defect positions of conventional carbon materials, on which pyridinic nitrogen can be selectively doped. The as-synthesized pyridinic nitrogen-doped hydrogen-substituted graphdiyne shows much better electrocatalytic performance for the oxygen reduction reaction than that of the commercial platinum-based catalyst in alkaline media and comparable activity in acidic media. Density functional theory calculations demonstrate that the pyridinic nitrogen-doped hydrogen-substituted graphdiyne is more effective than pyridinic nitrogen-doped graphene for oxygen reduction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000442521500001 |
| 出版者 | NATURE PUBLISHING GROUP |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42465]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Changshui; Li, Yuliang |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Qingdao Univ, 308 Ningxia Rd, Qingdao 266071, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Beijing Computat Sci Res Ctr, 10 East Xibeiwang Rd Haidian Dist, Beijing 100193, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 6.Shandong Univ, Inst Mol Sci & Engn, 72 Binhai Rd, Qingdao 266235, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Qing,Si, Wenyan,He, Jianjiang,et al. Selectively nitrogen-doped carbon materials as superior metal-free catalysts for oxygen reduction[J]. NATURE COMMUNICATIONS,2018,9. |
| APA | Lv, Qing.,Si, Wenyan.,He, Jianjiang.,Sun, Lei.,Zhang, Chunfang.,...&Li, Yuliang.(2018).Selectively nitrogen-doped carbon materials as superior metal-free catalysts for oxygen reduction.NATURE COMMUNICATIONS,9. |
| MLA | Lv, Qing,et al."Selectively nitrogen-doped carbon materials as superior metal-free catalysts for oxygen reduction".NATURE COMMUNICATIONS 9(2018). |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。