Cascade C(sp(3))-S Bond Cleavage and Imidoyl C-S Formation: Radical Cyclization of 2-Isocyanoaryl Thioethers toward 2-Substituted Benzothiazoles
文献类型：期刊论文
| 作者 | Yang, Wen-Chao1,2,5; Wei, Kai1,2; Sun, Xue1,2; Zhu, Jie1,2; Wu, Lei1,2,3,4 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2018-05-18 |
| 卷号 | 20期号:10页码:3144-3147 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.8b01278 |
| 英文摘要 | A cascade radical cyclization of 2-isocyanoaryl thioethers with H-phosphorus oxides, organoboronic acids, or alkyl radical precursors has been efficiently developed, providing a novel and highly efficient methodology to structurally diverse C2-substituted benzothiazole derivatives with broad functional group tolerance and good yields. This cascade radical process achieves the first cycloaddition of an imidoyl radical from isocyanide to sulfur atom, rending C(sp(2))-S bond formation. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000432900200080 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42491]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, Lei |
| 作者单位 | 1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 5.Nanjing Agr Univ, Coll Plant Protect, Nanjing 210095, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Wen-Chao,Wei, Kai,Sun, Xue,et al. Cascade C(sp(3))-S Bond Cleavage and Imidoyl C-S Formation: Radical Cyclization of 2-Isocyanoaryl Thioethers toward 2-Substituted Benzothiazoles[J]. ORGANIC LETTERS,2018,20(10):3144-3147. |
| APA | Yang, Wen-Chao,Wei, Kai,Sun, Xue,Zhu, Jie,&Wu, Lei.(2018).Cascade C(sp(3))-S Bond Cleavage and Imidoyl C-S Formation: Radical Cyclization of 2-Isocyanoaryl Thioethers toward 2-Substituted Benzothiazoles.ORGANIC LETTERS,20(10),3144-3147. |
| MLA | Yang, Wen-Chao,et al."Cascade C(sp(3))-S Bond Cleavage and Imidoyl C-S Formation: Radical Cyclization of 2-Isocyanoaryl Thioethers toward 2-Substituted Benzothiazoles".ORGANIC LETTERS 20.10(2018):3144-3147. |
入库方式： OAI收割
来源：化学研究所
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