Stereoselective Total Synthesis of (+/-)-5-epi-Cyanthiwigin I via an Intramolecular Pauson-Khand Reaction as the Key Step
文献类型:期刊论文
作者 | Chang, Yuanyuan1; Shi, Linlin1; Huang, Jun1; Shi, Lili1; Zhang, Zichun1; Hao, Hong-Dong1; Gong, Jianxian1; Yang, Zhen1,2,3,4,5 |
刊名 | ORGANIC LETTERS
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出版日期 | 2018-05-18 |
卷号 | 20期号:10页码:2876-2879 |
ISSN号 | 1523-7060 |
DOI | 10.1021/acs.orglett.8b00903 |
英文摘要 | A convenient approach to the construction of the 5-6-7 tricarbocyclic fused core structure of cyanthiwigins via a Co-mediated Pauson-Khand reaction as a key step has been developed. The cyathane core intermediate obtained by this strategy was used in the concise synthesis of (+/-)-5-epi-cyanthiwigin I. The developed chemistry paves the way for the total synthesis of structurally diverse cyanthiwigins. |
语种 | 英语 |
WOS记录号 | WOS:000432900200018 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/42515] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Hao, Hong-Dong; Gong, Jianxian; Yang, Zhen |
作者单位 | 1.Peking Univ, State Key Lab Chem Oncogen, Key Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China 2.Peking Univ, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Peking Univ, BNLMS, Beijing 100871, Peoples R China 4.Peking Univ, Peking Tsinghua Ctr Life Sci, Beijing 100871, Peoples R China 5.Ocean Univ China, Sch Med & Pharm, Key Lab Marine Drugs, Chinese Minist Educ, 5 Yushan Rd, Qingdao 266071, Peoples R China |
推荐引用方式 GB/T 7714 | Chang, Yuanyuan,Shi, Linlin,Huang, Jun,et al. Stereoselective Total Synthesis of (+/-)-5-epi-Cyanthiwigin I via an Intramolecular Pauson-Khand Reaction as the Key Step[J]. ORGANIC LETTERS,2018,20(10):2876-2879. |
APA | Chang, Yuanyuan.,Shi, Linlin.,Huang, Jun.,Shi, Lili.,Zhang, Zichun.,...&Yang, Zhen.(2018).Stereoselective Total Synthesis of (+/-)-5-epi-Cyanthiwigin I via an Intramolecular Pauson-Khand Reaction as the Key Step.ORGANIC LETTERS,20(10),2876-2879. |
MLA | Chang, Yuanyuan,et al."Stereoselective Total Synthesis of (+/-)-5-epi-Cyanthiwigin I via an Intramolecular Pauson-Khand Reaction as the Key Step".ORGANIC LETTERS 20.10(2018):2876-2879. |
入库方式: OAI收割
来源:化学研究所
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