中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Graphene Oxide-Based Fe-Mg (Hydr)oxide Nanocomposite as Heavy Metals Adsorbent

文献类型:期刊论文

作者Huang, Dayong1,2; Li, Boxuan1; Wu, Min1; Kuga, Shigenori1; Huang, Yong1
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
出版日期2018-06-01
卷号63期号:6页码:2097-2105
ISSN号0021-9568
DOI10.1021/acs.jced.8b00100
英文摘要A novel adsorbent for divalent metal cations 600 was prepared as nanocomposite of Fe-Mg (hydr)oxide with graphene oxide by one-step coprecipitation. This material showed adsorption selectivity of Pb2+ > Cu2+ > Ag+ > Zn2+ >> CO2+, Ni2+, Cd2+ with high adsorption capacity of 100-600 mg/g for Pb2+, Cu2+, Ag+, and Zn2+. Distribution coefficient (K-d) was as high as similar to 10(7) mL/g for Pb2+ and Cu2+. The adsorption isotherms for Pb2+, Cu2+, Ag+, and Zn2+ followed the Langmuir model, indicating monolayer adsorption. The adsorption kinetics for Pb2+, Cu2+, Ag+, and Zn2+ followed pseudo-second-order model, suggesting chemisorption. Removal of 50 ppm Pb2+ or Cu2+ from 100 mL solution by 0.1 g of the nanocomposite was over 99.7%. The thermodynamics studies implied that the adsorption process toward heavy metals was spontaneous and endothermic. Together with recyclability through magnetic separation, this adsorbent would be useful in polluted water processing.
语种英语
WOS记录号WOS:000435613000029
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/42527]  
专题中国科学院化学研究所
通讯作者Wu, Min; Huang, Yong
作者单位1.Chinese Acad Sci, Natl Engn Res Ctr Engn Plast, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Huang, Dayong,Li, Boxuan,Wu, Min,et al. Graphene Oxide-Based Fe-Mg (Hydr)oxide Nanocomposite as Heavy Metals Adsorbent[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2018,63(6):2097-2105.
APA Huang, Dayong,Li, Boxuan,Wu, Min,Kuga, Shigenori,&Huang, Yong.(2018).Graphene Oxide-Based Fe-Mg (Hydr)oxide Nanocomposite as Heavy Metals Adsorbent.JOURNAL OF CHEMICAL AND ENGINEERING DATA,63(6),2097-2105.
MLA Huang, Dayong,et al."Graphene Oxide-Based Fe-Mg (Hydr)oxide Nanocomposite as Heavy Metals Adsorbent".JOURNAL OF CHEMICAL AND ENGINEERING DATA 63.6(2018):2097-2105.

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来源:化学研究所

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