Competition between Arene-Perfluoroarene and Charge-Transfer Interactions in Organic Light-Harvesting Systems
文献类型：期刊论文
| 作者 | Sun, Yanqiu1,7; Lei, Yilong4,5; Liao, Liangsheng6; Hu, Wenping1,2,3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-08-21 |
| 卷号 | 56期号:35页码:10352-10356 |
| 关键词 | Arene-perfluoroarene Complexes Charge-transfer Systems Cocrystals Energy Transfers Organic Light-harvesting Systems |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201702084 |
| 英文摘要 | Two typical types of luminescent organic cocrystals comprising pyrene-octafluoronaphthalene (pyrene-OFN) and pyrene-1,2,4,5-tetracyanobezene (pyrene-TCNB) were developed by a simple supramolecular assembly strategy. The cocrystals exhibit distinct optical properties because of their different intermolecular interaction modes; that is, areneperfluoroarene (AP) and charge-transfer (CT) interactions. Unexpectedly, a pyrene-TCNB system with strong CT interactions was incorporated into a pyrene-OFN host as a robust guest to generate white-light emission (WLE). In the supramolecular cocrystal system, an efficient energy-transfer process from pyrene-OFN to pyrene-TCNB occurred because of the well-matched spectra of the constituents and a desirable energy donor/acceptor (D/A) distance. The present competitive intermolecular interaction strategy could be applied to the fabrication of more complicated organic light-harvesting systems. |
| 语种 | 英语 |
| WOS记录号 | WOS:000434546000010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42667]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hu, Wenping |
| 作者单位 | 1.Chinese Acad Sci ICCAS, Inst Chem, Beijing 100190, Peoples R China 2.Tianjin Univ, Key Lab Mol Optoelect Sci, Sch Sci, Tianjin 300072, Peoples R China 3.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China 4.Hong Kong Baptist Univ, Dept Chem, Inst Mol Funct Mat, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China 5.Hong Kong Baptist Univ, Inst Adv Mat, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China 6.Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Suzhou, Jiangsu 215123, Peoples R China 7.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Yanqiu,Lei, Yilong,Liao, Liangsheng,et al. Competition between Arene-Perfluoroarene and Charge-Transfer Interactions in Organic Light-Harvesting Systems[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(35):10352-10356. |
| APA | Sun, Yanqiu,Lei, Yilong,Liao, Liangsheng,&Hu, Wenping.(2017).Competition between Arene-Perfluoroarene and Charge-Transfer Interactions in Organic Light-Harvesting Systems.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(35),10352-10356. |
| MLA | Sun, Yanqiu,et al."Competition between Arene-Perfluoroarene and Charge-Transfer Interactions in Organic Light-Harvesting Systems".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.35(2017):10352-10356. |
入库方式： OAI收割
来源：化学研究所
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