Cu(I)-Catalyzed Coupling of Bis(trimethylsilyl)diazomethane with Terminal Alkynes: A Synthesis of 1,1-Disilyl Allenes
文献类型：期刊论文
| 作者 | Xu, Shuai1; Chen, Ri1; Fu, Zihao1; Gao, Yunpeng1; Wang, Jianbo1,2 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2018-06-01 |
| 卷号 | 83期号:11页码:6186-6192 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acsjoc.8b00651 |
| 英文摘要 | A Cu(I)-catalyzed cross-coupling reaction of terminal alkynes and bis(trimethylsilyl)diazomethane is reported. Mechanistically, the reaction is based on the recently developed cross-coupling reactions through metal-carbene migratory insertion. This reaction provides an efficient synthetic method for 1,1-disilyl allenes. Subsequent transformations of 1,1-disilyl allenes are investigated, which show diverse reactivities of these allenes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000434367700030 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42697]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Shuai,Chen, Ri,Fu, Zihao,et al. Cu(I)-Catalyzed Coupling of Bis(trimethylsilyl)diazomethane with Terminal Alkynes: A Synthesis of 1,1-Disilyl Allenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(11):6186-6192. |
| APA | Xu, Shuai,Chen, Ri,Fu, Zihao,Gao, Yunpeng,&Wang, Jianbo.(2018).Cu(I)-Catalyzed Coupling of Bis(trimethylsilyl)diazomethane with Terminal Alkynes: A Synthesis of 1,1-Disilyl Allenes.JOURNAL OF ORGANIC CHEMISTRY,83(11),6186-6192. |
| MLA | Xu, Shuai,et al."Cu(I)-Catalyzed Coupling of Bis(trimethylsilyl)diazomethane with Terminal Alkynes: A Synthesis of 1,1-Disilyl Allenes".JOURNAL OF ORGANIC CHEMISTRY 83.11(2018):6186-6192. |
入库方式： OAI收割
来源：化学研究所
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