Zirconocene mediated acetylboron chemistry
文献类型：期刊论文
| 作者 | Jian, Zhongbao1,2; Daniliuc, Constantin G.1; Kehr, Gerald1; Erker, Gerhard1 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2018-06-07 |
| 卷号 | 54期号:45页码:5724-5727 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c8cc02680g |
| 英文摘要 | The methyl zirconocene complex Cp*Zr-2(Me)OMes reacts with H3C-B(C6F5)(2) and CO to give the respective acetyl(methyl)borate Zr complex. Cp*Zr-2(H)OMes reacts with H3C-B(C6F5)(2) and CO to give the respective acetyl(hydrido)borate Zr product, admixed with a minor amount of the formyl(methyl)borate Zr complex isomer. Prolonged exposure to CO under close to ambient conditions results in the uptake of another CO equivalent to yield the corresponding borata--lactone zirconocene product. |
| 语种 | 英语 |
| WOS记录号 | WOS:000434314500012 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42735]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Erker, Gerhard |
| 作者单位 | 1.Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Renmin St 5625, Changchun 130022, Jilin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jian, Zhongbao,Daniliuc, Constantin G.,Kehr, Gerald,et al. Zirconocene mediated acetylboron chemistry[J]. CHEMICAL COMMUNICATIONS,2018,54(45):5724-5727. |
| APA | Jian, Zhongbao,Daniliuc, Constantin G.,Kehr, Gerald,&Erker, Gerhard.(2018).Zirconocene mediated acetylboron chemistry.CHEMICAL COMMUNICATIONS,54(45),5724-5727. |
| MLA | Jian, Zhongbao,et al."Zirconocene mediated acetylboron chemistry".CHEMICAL COMMUNICATIONS 54.45(2018):5724-5727. |
入库方式： OAI收割
来源：化学研究所
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