Catalytic Asymmetric Oxidative Enamine Transformations
文献类型：期刊论文
| 作者 | Zhu, Lihui1,2; Wang, Dehong1,2; Jia, Zongbin1,2; Lin, Qifeng1,2; Huang, Mouxin3; Luo, Sanzhong1,2,3,4 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2018-06-01 |
| 卷号 | 8期号:6页码:5466-5484 |
| ISSN号 | 2155-5435 |
| 关键词 | Organocatalysis Aminocatalysis Enamine Transformation Oxidative Enamine Catalysis Nucleophile |
| DOI | 10.1021/acscatal.8b01263 |
| 英文摘要 | Enamine catalysis is a prevalent strategy for the fiinctionalization of aldehydes/ketones with electrophiles. Recently, the advent and development of oxidative enamine catalysis have allowed for the coupling of enamines with readily available nucleophiles under oxidative conditions, significantly expanding the domain of typical enamine catalysis. In this perspective, we summarize the recent advances in asymmetric oxidative enamine catalysis. On the basis of the oxidative strategy, these could be classified as (1) oxidation of nucleophile, (2) oxidation of enamine via single-electron transfer (SOMO catalysis), and (3) oxidation of enamine to alpha,beta-unsaturated iminium ion, i.e. oxidative iminium catalysis. These strategies have enabled efficient oxidative functionalizations of aldehydes/ketones with various O-, N-, and C-centered nucleophiles in a highly stereocontrolled manner. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000434369600077 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42739]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Luo, Sanzhong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100490, Peoples R China 3.Tsinghua Univ, CBMS, Dept Chem, Beijing 100084, Peoples R China 4.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Lihui,Wang, Dehong,Jia, Zongbin,et al. Catalytic Asymmetric Oxidative Enamine Transformations[J]. ACS CATALYSIS,2018,8(6):5466-5484. |
| APA | Zhu, Lihui,Wang, Dehong,Jia, Zongbin,Lin, Qifeng,Huang, Mouxin,&Luo, Sanzhong.(2018).Catalytic Asymmetric Oxidative Enamine Transformations.ACS CATALYSIS,8(6),5466-5484. |
| MLA | Zhu, Lihui,et al."Catalytic Asymmetric Oxidative Enamine Transformations".ACS CATALYSIS 8.6(2018):5466-5484. |
入库方式： OAI收割
来源：化学研究所
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