A highly efficient Ni-Mo bimetallic hydrogen evolution catalyst derived from a molybdate incorporated Ni-MOF
文献类型：期刊论文
| 作者 | Wang, Teng1; Jin, Rumei1; Wu, Xiuqi1; Zheng, Jie1; Li, Xingguo1; Ostrikov, Kostya2,3 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2018-05-21 |
| 卷号 | 6期号:19页码:9228-9235 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta01325j |
| 英文摘要 | A highly efficient Ni-Mo bimetallic catalyst for the hydrogen evolution reaction can be obtained from a molybdate incorporated Ni-MOF by thermal decomposition in NH3. The catalyst is composed of crystalline Ni nanoparticles doped with amorphous low valence Mo oxide encapsulated in thin N-doped carbon layers, showing excellent HER performance, featuring a very low overpotential for the HER (eta(20) = 58 mV), low Tafel slope (57 mV dec(-1)) and excellent long term stability. The catalyst apparently outperforms N-doped carbon encapsulated Ni catalysts without Mo doping, emphasizing the critical synergetic effect of Mo doping and the surface N-doped carbon thin layer on promoting the performance of Ni based HER catalysts. |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000434625200049 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42797]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zheng, Jie; Li, Xingguo |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China 2.Queensland Univ Technol, Sch Chem Phys & Mech Engn, Inst Hlth & Biomed Innovat, Inst Future Environm, Brisbane, Qld 4000, Australia 3.CSIRO QUT Joint Sustainable Proc & Devices Lab, POB 218, Lindfield, NSW, Australia |
| 推荐引用方式 GB/T 7714 | Wang, Teng,Jin, Rumei,Wu, Xiuqi,et al. A highly efficient Ni-Mo bimetallic hydrogen evolution catalyst derived from a molybdate incorporated Ni-MOF[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(19):9228-9235. |
| APA | Wang, Teng,Jin, Rumei,Wu, Xiuqi,Zheng, Jie,Li, Xingguo,&Ostrikov, Kostya.(2018).A highly efficient Ni-Mo bimetallic hydrogen evolution catalyst derived from a molybdate incorporated Ni-MOF.JOURNAL OF MATERIALS CHEMISTRY A,6(19),9228-9235. |
| MLA | Wang, Teng,et al."A highly efficient Ni-Mo bimetallic hydrogen evolution catalyst derived from a molybdate incorporated Ni-MOF".JOURNAL OF MATERIALS CHEMISTRY A 6.19(2018):9228-9235. |
入库方式： OAI收割
来源：化学研究所
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