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N-doped carbon supported Pd catalysts for N-formylation of amines with CO2/H-2

文献类型：期刊论文

作者Luo, Xiaoying1,2; Zhang, Hongye1; Ke, Zhengang1,2; Wu, Cailing1,2; Guo, Shien1,2; Wu, Yunyan1,2; Yu, Bo1; Liu, Zhimin1,2
刊名SCIENCE CHINA-CHEMISTRY
出版日期2018-06-01
卷号61期号:6页码:725-731
关键词Pd/nc C-n Formation N-formylation Co2 H-2
ISSN号1674-7291
DOI10.1007/s11426-017-9215-2
英文摘要Using mesoporous N-doped carbons (NCs) derived from glucose and melamine as the supports, a series of Pd/NC catalysts were prepared, in which Pd nanoparticles with average size < 2.0 nm were uniformly distributed on the supports. It was indicated that the resultant Pd/NC catalysts were effective for N-formylation of amines with CO2 and H-2 in ethanol without any additives. Especially, the catalyst Pd/NC-800-6.9% containing quaternary N showed the best performance, affording a series of formylamides in good or even excellent yields. Further investigation reveals that the interaction between the Pd nanoparticles and quaternary nitrogen in the NC support was responsible for the good performance of the catalyst.
语种英语
WOS记录号WOS:000434719100016
出版者SCIENCE PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/42833]  
专题中国科学院化学研究所
通讯作者Liu, Zhimin
作者单位1.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Key Lab Colloid Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Luo, Xiaoying,Zhang, Hongye,Ke, Zhengang,et al. N-doped carbon supported Pd catalysts for N-formylation of amines with CO2/H-2[J]. SCIENCE CHINA-CHEMISTRY,2018,61(6):725-731.
APA Luo, Xiaoying.,Zhang, Hongye.,Ke, Zhengang.,Wu, Cailing.,Guo, Shien.,...&Liu, Zhimin.(2018).N-doped carbon supported Pd catalysts for N-formylation of amines with CO2/H-2.SCIENCE CHINA-CHEMISTRY,61(6),725-731.
MLA Luo, Xiaoying,et al."N-doped carbon supported Pd catalysts for N-formylation of amines with CO2/H-2".SCIENCE CHINA-CHEMISTRY 61.6(2018):725-731.

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来源：化学研究所

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