Mo-Bi-Cd Ternary Metal Chalcogenides: Highly Efficient Photocatalyst for CO2 Reduction to Formic Acid Under Visible Light
文献类型：期刊论文
| 作者 | Zhou, Baowen1; Song, Jinliang1; Xie, Chao1,2; Chen, Chunjun1,2; Qian, Qingli1; Han, Buxing1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 6期号:5页码:5754-5759 |
| 关键词 | Mo-bi-cd Chalcogenides Visible-light-driven Co2 Reduction Formic Acid Ionic Liquid Photocatalysis |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.8b00956 |
| 英文摘要 | The exploration of efficient and cheap photocatalysts for the transformation of CO2 into value-added chemicals is of great importance. Herein, we carried out the work on CO2 reduction using ternary metal chalcogenides as photocatalysts. It was found that the ternary metal chalcogenides of (MoBi)Sx supported on mesoporous CdS ((Mo-Bi)S-x/Meso CdS) was very active and selective for photocatalytic reduction of CO2 to HCOOH in 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4)acetonitrile (MeCN) mixed solvent under visible light. HCOOH was the only carbonaceous product and H-2 was the only byproduct. The rate of HCOOH formation could be as high as 208 mu mol.g(-1).h(-1) with a 72% faradaic efficiency. The synergistic effect of the components played a key role for the outstanding performance of the catalyst; the catalyst and [Bmim]BF4 further cooperated in promoting the reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000431927500012 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42847]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, 1st North St Zhongguancun, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Yuquan Rd 19, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Baowen,Song, Jinliang,Xie, Chao,et al. Mo-Bi-Cd Ternary Metal Chalcogenides: Highly Efficient Photocatalyst for CO2 Reduction to Formic Acid Under Visible Light[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(5):5754-5759. |
| APA | Zhou, Baowen,Song, Jinliang,Xie, Chao,Chen, Chunjun,Qian, Qingli,&Han, Buxing.(2018).Mo-Bi-Cd Ternary Metal Chalcogenides: Highly Efficient Photocatalyst for CO2 Reduction to Formic Acid Under Visible Light.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(5),5754-5759. |
| MLA | Zhou, Baowen,et al."Mo-Bi-Cd Ternary Metal Chalcogenides: Highly Efficient Photocatalyst for CO2 Reduction to Formic Acid Under Visible Light".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.5(2018):5754-5759. |
入库方式： OAI收割
来源：化学研究所
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