Production of Formamides from CO and Amines Induced by Porphyrin Rhodium(II) Metalloradical
文献类型：期刊论文
| 作者 | Zhang, Jiajing1; Zhang, Wentao1; Xu, Minghui1; Zhang, Yang1; Fu, Xuefeng1; Fang, Huayi2 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2018-05-30 |
| 卷号 | 140期号:21页码:6656-6660 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.8b03029 |
| 英文摘要 | It is of fundamental importance to transform carbon monoxide (CO) to petrochemical feedstocks and fine chemicals. Many strategies built on the activation of C O bond by pi-back bonding from the transition metal center were developed during the past decades. Herein, a new CO activation method, in which the CO was converted to the active acyl-like metalloradical, [(por)Rh(CO)](center dot) (por = porphyrin), was reported. The reactivity of Rpor)Rh(CO)](center dot) and other rhodium porphyrin compounds, such as (por)RhCHO and (por)RhC(O)(NHPr)-Pr-n, and corresponding mechanism studies were conducted experimentally and computationally and inspired the design of a new conversion system featuring 100% atom economy that promotes carbonylation of amines to formamides using porphyrin rhodium(II) metalloradical. Following this radical based pathway, the carbonylations of a series of primary and secondary aliphatic amines were examined, and turnover numbers up to 224 were obtained. |
| 语种 | 英语 |
| WOS记录号 | WOS:000434101100022 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42877]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fang, Huayi |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jiajing,Zhang, Wentao,Xu, Minghui,et al. Production of Formamides from CO and Amines Induced by Porphyrin Rhodium(II) Metalloradical[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(21):6656-6660. |
| APA | Zhang, Jiajing,Zhang, Wentao,Xu, Minghui,Zhang, Yang,Fu, Xuefeng,&Fang, Huayi.(2018).Production of Formamides from CO and Amines Induced by Porphyrin Rhodium(II) Metalloradical.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(21),6656-6660. |
| MLA | Zhang, Jiajing,et al."Production of Formamides from CO and Amines Induced by Porphyrin Rhodium(II) Metalloradical".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.21(2018):6656-6660. |
入库方式： OAI收割
来源：化学研究所
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