Palladium-Catalyzed Cascade C-O Cleavage and C-H Alkenylation of Phosphinyl Allenes: An Expeditious Approach to 3-Alkenyl Benzo[b]phosphole Oxides
文献类型：期刊论文
| 作者 | Liu, Teng1,2; Sun, Xue1,2; Wu, Lei1,2,3 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2018-05-16 |
| 卷号 | 360期号:10页码:2005-2012 |
| ISSN号 | 1615-4150 |
| 关键词 | 3-alkenyl Benzo[b]Phosphole Oxides C-o Cleavage C-h Alkenylation Phosphinyl Allenes Palladium Catalysis |
| DOI | 10.1002/adsc.201800103 |
| 英文摘要 | A phosphine oxide-directed intramolecular cyclization of phosphinyl allenes is established for the first time. The palladium-catalyzed intramolecular cyclization provides an unprecedented cascade C-O cleavage and direct C-H alkenylation toward novel 3-alkenyl benzo[b]phosphole oxides, along with broad group tolerance and high regioselectivity. Control experiments and mechanistic studies explain the sequential performance of C(sp(3))-OAr cleavage and P=O directed C(sp(2))-H activation. |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000432704400015 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42885]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wu, Lei |
| 作者单位 | 1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Dept Chem, Coll Sci, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Teng,Sun, Xue,Wu, Lei. Palladium-Catalyzed Cascade C-O Cleavage and C-H Alkenylation of Phosphinyl Allenes: An Expeditious Approach to 3-Alkenyl Benzo[b]phosphole Oxides[J]. ADVANCED SYNTHESIS & CATALYSIS,2018,360(10):2005-2012. |
| APA | Liu, Teng,Sun, Xue,&Wu, Lei.(2018).Palladium-Catalyzed Cascade C-O Cleavage and C-H Alkenylation of Phosphinyl Allenes: An Expeditious Approach to 3-Alkenyl Benzo[b]phosphole Oxides.ADVANCED SYNTHESIS & CATALYSIS,360(10),2005-2012. |
| MLA | Liu, Teng,et al."Palladium-Catalyzed Cascade C-O Cleavage and C-H Alkenylation of Phosphinyl Allenes: An Expeditious Approach to 3-Alkenyl Benzo[b]phosphole Oxides".ADVANCED SYNTHESIS & CATALYSIS 360.10(2018):2005-2012. |
入库方式： OAI收割
来源：化学研究所
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