Single Cr atom catalytic growth of graphene
文献类型：期刊论文
| 作者 | Ta, Huy Q.1,2,3,4; Zhao, Liang1,2,3; Yin, Wanjian1,2,3; Pohl, Darius5; Rellinghaus, Bernd5; Gemming, Thomas5; Trzebicka, Barbara4; Palisaitis, Justinas6; Jing, Gao1,2,3; Persson, Per O. A.6 |
| 刊名 | NANO RESEARCH
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 11期号:5页码:2405-2411 |
| 关键词 | In Situ Transmission Electron Microscope (Tem) Electron Driven Catalysis Cr Single Atom Graphene Synthesis |
| ISSN号 | 1998-0124 |
| DOI | 10.1007/s12274-017-1861-3 |
| 英文摘要 | Single atoms are the ultimate minimum size limit for catalysts. Graphene, as an exciting, ultimately thin (one atom thick) material can be imaged in a transmission electron microscope with relatively few imaging artefacts. Here, we directly observe the behavior of single Cr atoms in graphene mono- and di-vacancies and, more importantly, at graphene edges. Similar studies at graphene edges with other elemental atoms, with the exception of Fe, show catalytic etching of graphene. Fe atoms have been shown to both etch and grow graphene. In contrast, Cr atoms are only observed to induce graphene growth. Complementary theoretical calculations illuminate the differences between Fe and Cr, and confirm single Cr atoms as superior catalysts for sp(2) carbon growth. |
| 语种 | 英语 |
| WOS记录号 | WOS:000431999700008 |
| 出版者 | TSINGHUA UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42899]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yin, Wanjian; Bachmatiuk, Alicja; Rummeli, Mark H. |
| 作者单位 | 1.Soochow Univ, Coll Phys Optoelect & Energy, Soochow Inst Energy & Mat Innovat, Suzhou 215006, Peoples R China 2.Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215006, Peoples R China 3.Soochow Univ, Key Lab Adv Carbon Mat & Wearable Energy Technol, Suzhou 215006, Peoples R China 4.Polish Acad Sci, Ctr Polymer & Carbon Mat, M Curie Sklodowskiej 34, PL-41819 Zabrze, Poland 5.IFW Dresden, Helmholtz Str 20, D-01069 Dresden, Germany 6.Linkoping Univ, Dept Phys Chem & Biol IFM, SE-58183 Linkoping, Sweden 7.Peking Univ, Beijing Sci & Engn Ctr Nanocarbons, Coll Chem & Mol Engn, Ctr Nanochem,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ta, Huy Q.,Zhao, Liang,Yin, Wanjian,et al. Single Cr atom catalytic growth of graphene[J]. NANO RESEARCH,2018,11(5):2405-2411. |
| APA | Ta, Huy Q..,Zhao, Liang.,Yin, Wanjian.,Pohl, Darius.,Rellinghaus, Bernd.,...&Rummeli, Mark H..(2018).Single Cr atom catalytic growth of graphene.NANO RESEARCH,11(5),2405-2411. |
| MLA | Ta, Huy Q.,et al."Single Cr atom catalytic growth of graphene".NANO RESEARCH 11.5(2018):2405-2411. |
入库方式： OAI收割
来源：化学研究所
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