Silicone-Epoxy-Based Hybrid Photopolymers for 3D Printing
文献类型：期刊论文
| 作者 | Zhao, Tingting1,2; Li, Xinpan1,2; Yu, Ran1; Zhang, Ying1; Yang, Xin1; Zhao, Xiaojuan1; Wang, Lei1; Huang, Wei1,2 |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 219期号:10 |
| 关键词 | 3d Printing Acrylate Hybrid Photopolymers Silicone-epoxy Stereolithography |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.201700530 |
| 英文摘要 | In the present research, a type of cycloaliphatic silicone-epoxy resin is synthesized and then compounded with acrylates as well as photoinitiators to obtain hybrid photopolymers. The photocuring rate of the hybrid photopolymers, the morphology, thermal and mechanical properties of the cured samples with different silicone-epoxy/acrylate ratios are studied in detail. Scanning electron microscopy images prove that interpenetrating polymer network structure is formed. To improve the mechanical properties, diglycidyl ether of bisphenol A is added and finally a type of hybrid photopolymer suitable for stereolithography 3D printing is obtained. Fourier-transform infrared spectroscopy and photo-differential scanning calorimeter measurements show that the hybrid photopolymer has a high curing rate, while thermal property tests prove that the cured sample has high thermal stability. Mechanical property tests show that the cured samples have a tensile strength of 40.3 MPa with a break elongation of 6.7%. The objects printed with the hybrid photopolymer exhibit high resolution and dimension accuracy. |
| 语种 | 英语 |
| WOS记录号 | WOS:000434149200001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42937]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yu, Ran; Huang, Wei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Tingting,Li, Xinpan,Yu, Ran,et al. Silicone-Epoxy-Based Hybrid Photopolymers for 3D Printing[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2018,219(10). |
| APA | Zhao, Tingting.,Li, Xinpan.,Yu, Ran.,Zhang, Ying.,Yang, Xin.,...&Huang, Wei.(2018).Silicone-Epoxy-Based Hybrid Photopolymers for 3D Printing.MACROMOLECULAR CHEMISTRY AND PHYSICS,219(10). |
| MLA | Zhao, Tingting,et al."Silicone-Epoxy-Based Hybrid Photopolymers for 3D Printing".MACROMOLECULAR CHEMISTRY AND PHYSICS 219.10(2018). |
入库方式： OAI收割
来源：化学研究所
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