Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines
文献类型：期刊论文
| 作者 | Zhu, Yanan1,2; Yang, Shuliang1; Cao, Changyan1,2; Song, Weiguo1,2; Wan, Li-Jun1 |
| 刊名 | INORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 5期号:5页码:1094-1099 |
| ISSN号 | 2052-1553 |
| DOI | 10.1039/c7qi00803a |
| 英文摘要 | Selective hydrogenation of nitroarenes is an important chemical transformation to obtain functionalized anilines as key intermediates for pharmaceuticals and fine chemicals. Compared to the well-studied noble metal catalysts, heterogeneous catalysts based on low-cost transition metals are rarely reported. In this study, we developed an efficient and controllable route to synthesize a new kind of heterogeneous catalyst of iron phosphide nanoparticles encapsulated in a doped carbon matrix for the chemoselective hydrogenation of aromatic nitroarenes to anilines. Making use of the chemical reaction between Fe atoms in a MIL-88B-NH2 core and phosphorus atoms in a poly(cyclotriphosphazene-co-4,4-sulfonyldiphenol) (PZS) shell, iron phosphide nanoparticles encapsulated in a doped carbon matrix were successfully prepared through direct calcinations of a Fe-MOF@PZS core@shell precursor at 900 degrees C for 2 h under an Ar atmosphere. Due to the relative high surface area and porous structure as well as small nanoparticles, the prepared catalyst showed high catalytic activity, excellent selectivity and recyclability for the hydrogenation of aromatic nitroarenes to anilines. |
| 语种 | 英语 |
| WOS记录号 | WOS:000432586100012 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/42949]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cao, Changyan; Song, Weiguo |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Lab Mol Nanostruct & Nanotechnol, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Yanan,Yang, Shuliang,Cao, Changyan,et al. Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines[J]. INORGANIC CHEMISTRY FRONTIERS,2018,5(5):1094-1099. |
| APA | Zhu, Yanan,Yang, Shuliang,Cao, Changyan,Song, Weiguo,&Wan, Li-Jun.(2018).Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines.INORGANIC CHEMISTRY FRONTIERS,5(5),1094-1099. |
| MLA | Zhu, Yanan,et al."Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines".INORGANIC CHEMISTRY FRONTIERS 5.5(2018):1094-1099. |
入库方式： OAI收割
来源：化学研究所
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