Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles
文献类型：期刊论文
| 作者 | Wang, Xiao-Dong1,2; Wu, Jin-Jin1,2; Sun, Xue1,2; Yang, Wen-Chao1,2; Zhu, Jie1,2; Wu, Lei1,2,3,4 |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2018-09-17 |
| 卷号 | 360期号:18页码:3518-3525 |
| 关键词 | Conjugated Enynes Phosphinyl Allenes Mof Palladium Nanoparticles |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.201800486 |
| 英文摘要 | A direct coupling of allenylphosphine oxides and alkynes is disclosed here mediated by MOF encapsulated palladium nanocatalysts. The methodology using alpha-allenyl ethers as starting materials provides a heterogeneous approach to generate tri-conjugated enynes with medium to excellent yields. The reaction tolerates a variety of functional groups to afford a range of structurally diverse substituted conjugated enynes. MOF served as support plays a significant role in dispersing and stabilizing the Pd nanoparticles. When compared with the homogeneous system, the advantage is also witnessed exhibiting a steady and high TOF value as well as the efficient reusability. A remarkable pore-control effect of the MOF catalysts was also revealed, depending on the dimension of MOF, molecular size of allenylphosphine oxides, alkynes and enynes respectively. Benefitting from the heterogeneous manner, successful recycling of the MOF catalyst was further achieved with high reaction efficiency maintained. |
| 语种 | 英语 |
| WOS记录号 | WOS:000444672200012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43001]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhu, Jie; Wu, Lei |
| 作者单位 | 1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiao-Dong,Wu, Jin-Jin,Sun, Xue,et al. Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles[J]. ADVANCED SYNTHESIS & CATALYSIS,2018,360(18):3518-3525. |
| APA | Wang, Xiao-Dong,Wu, Jin-Jin,Sun, Xue,Yang, Wen-Chao,Zhu, Jie,&Wu, Lei.(2018).Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles.ADVANCED SYNTHESIS & CATALYSIS,360(18),3518-3525. |
| MLA | Wang, Xiao-Dong,et al."Allenylphosphine Oxides as Starting Materials for the Synthesis of Conjugated Enynes: Boosting the Catalytic Performance by MOF Encapsulated Palladium Nanoparticles".ADVANCED SYNTHESIS & CATALYSIS 360.18(2018):3518-3525. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。