Prohibition of radiation-induced cross-linking of silica-reinforced silicone foam by oxygenation with H2O2
文献类型:期刊论文
| 作者 | Ao, Yinyong1; Cao, Ke2; Liu, Bo1; Wang, Pu-Cheng1; Chen, Hong-Bing1; Huang, Wei1; Jing, Peng2; Zhai, Maolin2 |
| 刊名 | RADIATION PHYSICS AND CHEMISTRY
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| 出版日期 | 2018-10-01 |
| 卷号 | 151页码:261-265 |
| 关键词 | Silicone Foam Radiation Cross-linking Oxygenation |
| ISSN号 | 0969-806X |
| DOI | 10.1016/j.radphyschem.2018.06.052 |
| 英文摘要 | Prohibition of radiation-induced cross-linking of silica-reinforced silicone foam by oxygenation with hydroxyl radicals generated from radiolysis of H2O2 solution was investigated. The elongation at break of samples irradiated under air decreases monotonically with irradiation, from a control value of 100 +/- 6.0% to 32.3 +/- 0.1% for samples exposed with a dose of 500 kGy. Compared to samples irradiated in air, the elongation at break of samples irradiated in H2O2 solution shows of a less decrease while that in H2O shows more of a decrease at the same dose. Our results indicate that radiolysis of H2O2 can weaken the increase of crosslink density of silicone foam, while H2O promotes the increase of crosslink density of silicone foam compared to that in air. The property and morphology changes of silicone foam are probably attributed to the irradiation induced crosslinking and radiolysis, the possible mechanisms for which are proposed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000444929500038 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43005] ![]() |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ao, Yinyong; Zhai, Maolin |
| 作者单位 | 1.China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Dept Appl Chem, BNLMS, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ao, Yinyong,Cao, Ke,Liu, Bo,et al. Prohibition of radiation-induced cross-linking of silica-reinforced silicone foam by oxygenation with H2O2[J]. RADIATION PHYSICS AND CHEMISTRY,2018,151:261-265. |
| APA | Ao, Yinyong.,Cao, Ke.,Liu, Bo.,Wang, Pu-Cheng.,Chen, Hong-Bing.,...&Zhai, Maolin.(2018).Prohibition of radiation-induced cross-linking of silica-reinforced silicone foam by oxygenation with H2O2.RADIATION PHYSICS AND CHEMISTRY,151,261-265. |
| MLA | Ao, Yinyong,et al."Prohibition of radiation-induced cross-linking of silica-reinforced silicone foam by oxygenation with H2O2".RADIATION PHYSICS AND CHEMISTRY 151(2018):261-265. |
入库方式: OAI收割
来源:化学研究所
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