Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines
文献类型：期刊论文
| 作者 | Hu, Yue1,2; Song, Jinliang1; Xie, Chao1,2; Wu, Haoran1,2; Wang, Zhenpeng1; Jiang, Tao1; Wu, Lei3; Wang, Yu3; Han, Buxing1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-09-01 |
| 卷号 | 6期号:9页码:11228-11234 |
| 关键词 | Transformation Of Carbon Dioxide Lecithin C-n Bond Construction Formylation And Methylation Renewable Organocatalyst |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.8b03245 |
| 英文摘要 | Transformation of carbon dioxide (CO2) into valuable chemicals is of great importance, and development of novel and efficient catalysts is crucial. Herein, we found that the renewable lecithin could be used as an efficient organocatalyst for the formylation and methylation of various amines with CO2 to corresponding formamides and methylamines via the construction of new C-N bonds using PhSiH3 as the hydrogen source, and satisfactory yields could be obtained. More importantly, the selectivity of the products could be easily controlled by the molar ratio of reactants (i.e., CO2, amines, and PhSiH3) and reaction temperature. In the catalytic cycle, formamides and methylamines were generated by converting the carbon (+4) in CO2 into +2 and -2 via 2-electron and 6-electron reduction pathway, respectively. |
| 语种 | 英语 |
| WOS记录号 | WOS:000443924100013 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43083]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Song, Jinliang; Jiang, Tao; Han, Buxing |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Colloid & Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci,Inst Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Zhejiang NHU Co Co LTD, Xinchang 312500, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Yue,Song, Jinliang,Xie, Chao,et al. Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(9):11228-11234. |
| APA | Hu, Yue.,Song, Jinliang.,Xie, Chao.,Wu, Haoran.,Wang, Zhenpeng.,...&Han, Buxing.(2018).Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(9),11228-11234. |
| MLA | Hu, Yue,et al."Renewable and Biocompatible Lecithin as an Efficient Organocatalyst for Reductive Conversion of CO2 with Amines to Formamides and Methylamines".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.9(2018):11228-11234. |
入库方式： OAI收割
来源：化学研究所
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