Radiation-induced grafting of 4-vinyl pyridine onto cellulose microsphere for Cr(VI) removal
文献类型:期刊论文
| 作者 | Zhang, Youwei1,2,3; Ma, Hui-Ling2,3,4; Peng, Jing2,3; Xu, Ling5; Li, Jiuqiang2,3; Zhai, Maolin2,3 |
| 刊名 | DESALINATION AND WATER TREATMENT
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| 出版日期 | 2018-02-01 |
| 卷号 | 105页码:255-263 |
| 关键词 | Cellulose Microsphere Radiation Grafting 4-vinyl Pyridine Adsorbent Cr(Vi) |
| ISSN号 | 1944-3994 |
| DOI | 10.5004/dwt.2018.21988 |
| 英文摘要 | A novel a mino-functionalized cellulose microsphere adsorbent (named C-VP) was prepared by radiation-induced grafting 4-vinyl pyridine (4VP) onto cellulose microsphere and subsequent protonation process. The graft polymerization conditions on the influence of grafting yield such as total absorbed dose, dose rate, solvent mixture ratio and monomer concentration, have been studied in detail. The obtained C-VP was tested for the abilities to remove Cr(VI) in batch experiments. The results demonstrated that the Cr(VI) adsorption was highly pH dependent and the maximum Cr(VI) uptake was obtained as the pH of solvent was 2.74. The adsorption isotherms of the C-VP for Cr(VI) fit the Langmuir model. The adsorption rate was considerably fast, and the adsorption reached equilibrium within 25 min. In addition, the Cr(VI) ions could be effectively desorbed using a 0.1 mol L-1 NaOH solution. Moreover, the reusability of the obtained C-VP was tested for several times and only slight loss in adsorption capacity was observed. Our work demonstrated the as-prepared adsorbent could possess a promising potential in the practical field of water treatment. |
| 语种 | 英语 |
| WOS记录号 | WOS:000445114700025 |
| 出版者 | DESALINATION PUBL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43097] ![]() |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhai, Maolin |
| 作者单位 | 1.Beijing Inst Aeronaut Mat, Aviat Key Lab Sci & Technol Stealth Mat, Beijing 100095, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Dept Appl Chem, Beijing 100871, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China 4.Beijing Res Ctr Radiat Applicat, Beijing Key Lab Radiat Adv Mat, Beijing 100015, Peoples R China 5.Peking Univ, Shenzhen Inst, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Youwei,Ma, Hui-Ling,Peng, Jing,et al. Radiation-induced grafting of 4-vinyl pyridine onto cellulose microsphere for Cr(VI) removal[J]. DESALINATION AND WATER TREATMENT,2018,105:255-263. |
| APA | Zhang, Youwei,Ma, Hui-Ling,Peng, Jing,Xu, Ling,Li, Jiuqiang,&Zhai, Maolin.(2018).Radiation-induced grafting of 4-vinyl pyridine onto cellulose microsphere for Cr(VI) removal.DESALINATION AND WATER TREATMENT,105,255-263. |
| MLA | Zhang, Youwei,et al."Radiation-induced grafting of 4-vinyl pyridine onto cellulose microsphere for Cr(VI) removal".DESALINATION AND WATER TREATMENT 105(2018):255-263. |
入库方式: OAI收割
来源:化学研究所
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