Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2
文献类型：期刊论文
| 作者 | Liu, Zhenghui1,2; Yang, Zhenzhen1; Yu, Bo1; Yu, Xiaoxiao1,2; Zhang, Hongye1; Zhao, Yanfei1; Yang, Peng1,2; Liu, Zhimin1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2018-09-07 |
| 卷号 | 20期号:17页码:5130-5134 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.8b02027 |
| 英文摘要 | The reductive formylation of aryl iodides/bromides to aryl aldehydes using CO2/H-2 is presented for the first time. It was realized over a catalytic system composed of RhI3 or RhI3/Pd(dppp)Cl-2 (dppp = 1,3-bis(diphenyphosphino)propane) and PPh3 in the presence of Ac2O/Et3N at 100 degrees C, affording aromatic aldehydes in good to excellent yields, together with good functional-group tolerance and broad substrate scope. The reaction proceeds through three cascade steps, involving HCOOH formation, CO release, and formylation of aryl halides. |
| 语种 | 英语 |
| WOS记录号 | WOS:000444527000013 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/43101]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Zhimin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Thermodynam, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Zhenghui,Yang, Zhenzhen,Yu, Bo,et al. Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2[J]. ORGANIC LETTERS,2018,20(17):5130-5134. |
| APA | Liu, Zhenghui.,Yang, Zhenzhen.,Yu, Bo.,Yu, Xiaoxiao.,Zhang, Hongye.,...&Liu, Zhimin.(2018).Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2.ORGANIC LETTERS,20(17),5130-5134. |
| MLA | Liu, Zhenghui,et al."Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H-2".ORGANIC LETTERS 20.17(2018):5130-5134. |
入库方式： OAI收割
来源：化学研究所
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